MEDLINE Journals

    Enantioselective alkylation of acyclic alpha,alpha-disubstituted tributyltin enolates catalyzed by a {Cr(salen)} complex.

    Authors
    Doyle AG, Jacobsen EN 
    Institution

    Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford St. Cambridge, MA 02138, USA.

    Source
    Angew Chem Int Ed Engl 2007; 46(20) :3701-5.
    Mesh
    Alkylation
    Catalysis
    Chromium
    Ketones
    Molecular Structure
    Organometallic Compounds
    Stereoisomerism
    Trialkyltin Compounds
    Language

    eng

    Pub Type(s)
    Journal Article Research Support, N.I.H., Extramural Research Support, U.S. Gov't, Non-P.H.S.
    PubMed ID

    17407117

    Content Manager
    Related Content

    		Enantioselective alkylations of tributyltin enolates catalyzed by Cr(salen)Cl: access to enantiomerically enriched all-carbon quaternary centers.

    		Enantioselective synthesis of alpha-tertiary hydroxyaldehydes by palladium-catalyzed asymmetric allylic alkylation of enolates.

    		Enantioselective synthesis of tertiary α-hydroxyketones from unfunctionalized ketones: palladium-catalyzed asymmetric allylic alkylation of enolates.

    		Enantioselective nitroaldol reaction catalyzed by sterically modified salen-chromium complexes.

    		Highly enantioselective conjugate additions to alpha,beta-unsaturated ketones catalyzed by a (salen)Al complex.

    		Enantioselective alkenylation via nickel-catalyzed cross-coupling with organozirconium reagents.

    		Ni(II)-catalyzed enantioselective conjugate addition of acetylenes to alpha,beta-enones.

    		Palladium-catalyzed synthesis of substituted cycloheptane-1,4-diones by an asymmetric ring-expanding allylation (AREA).