Enantioselective total synthesis of valeriananoids A-C. Organic letters. [Org Lett] Journal article

Title	Enantioselective total synthesis of valeriananoids A-C.
Author(s)	Srikrishna A, Satyanarayana G
Institution	Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India. ask@orgchem.iisc.ernet.in
Source	Org Lett 2004 Jul 8; 6(14):2337-9.
MeSH	Alkylation Catalysis Cyclization Indicators and Reagents Molecular Structure Monoterpenes Research Support, Non-U.S. Gov't Sesquiterpenes Stereoisomerism Terpenes Valerian
Abstract	[reaction: see text] The first enantioselective total synthesis of valeriananoids A-C (-)-1-3 is reported starting from the readily available monoterpene (R)-carvone, employing a tandem intermolecular Michael addition-intramolecular Michael addition-alkylation sequence and an electron-transfer-mediated 6-endo-trig cyclization as key steps.
Language	eng
Pub Type(s)	Journal Article
PubMed ID	15228273

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