Atom efficient cyclotrimerization of dimethylcyanamide catalyzed by aluminium amide: a combined experimental and theoretical investigation. Chemical communications (Cambridge, England) [Chem Commun (Camb)] Journal article | | Title | Atom efficient cyclotrimerization of dimethylcyanamide catalyzed by aluminium amide: a combined experimental and theoretical investigation. | | Author(s) | Dornan P, Rowley CN, Priem J, Barry ST, Burchell TJ, Woo TK, Richeson DS | | Institution | Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, Ottawa, Ontario, CanadaK1N 6N5. twoo@uottawa.ca darrin@uottawa.ca. | | Source | Chem Commun (Camb) 2008 Aug 21; (31):3645-7. | | Abstract | A novel method for the cyclotrimerization of dimethylcyanamide to form hexamethylmelamine has been developed using an aluminium amide catalyst; detailed DFT modelling of the catalytic cycle supports a triple insertion, nucleophilic ring closure, deinsertion mechanism. | | Language | eng | | Pub Type(s) | Journal Article
| | PubMed ID | 18665286 |
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