| Title | Preparation and properties of lithium and sodium peroxynitrite. | | Author(s) | Sturzbecher-Höhne M, Kissner R, Nauser T, Koppenol WH | | Institution | Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zurich, 8093 Zürich, Switzerland. | | Source | Chem Res Toxicol 2008 Dec; 21(12):2257-9. | | Abstract | We describe the preparation of aqueous solutions of LiONOO and NaONOO from (Me4N)ONOO. An aqueous solution of analytically pure, commercially available (Me4N)ONOO is applied to an Amberlyst 15 column at 4 degrees C, and the Me4N+ is rapidly (in 20 min) exchanged against Li+ or Na+. The exchanged peroxynitrite is produced in yields of ca. 90% with a nitrite content of 5-6%. | | Language | eng | | Pub Type(s) | Journal Article
Research Support, Non-U.S. Gov't
| | PubMed ID | 19548349 |
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