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Detection of perchlorate and the soluble chemistry of martian soil at the Phoenix lander site. Science (New York, N.Y.) [Science] Journal article

 
Hecht MH, Kounaves SP, Quinn RC, West SJ, Young SM, Ming DW, Catling DC, Clark BC, Boynton WV, Hoffman J, Deflores LP, Gospodinova K, Kapit J, Smith PH 
Detection of perchlorate and the soluble chemistry of martian soil at the Phoenix lander site. [Journal Article, Research Support, U.S. Gov't, Non-P.H.S.]
Science 2009 Jul 3; 325(5936):64-7.


The Wet Chemistry Laboratory on the Phoenix Mars Lander performed aqueous chemical analyses of martian soil from the polygon-patterned northern plains of the Vastitas Borealis. The solutions contained approximately 10 mM of dissolved salts with 0.4 to 0.6% perchlorate (ClO4) by mass leached from each sample. The remaining anions included small concentrations of chloride, bicarbonate, and possibly sulfate. Cations were dominated by Mg2+ and Na+, with small contributions from K+ and Ca2+. A moderately alkaline pH of 7.7 +/- 0.5 was measured, consistent with a carbonate-buffered solution. Samples analyzed from the surface and the excavated boundary of the approximately 5-centimeter-deep ice table showed no significant difference in soluble chemistry.



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