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TTMPP: An efficient organocatalyst in the ring-opening of aziridines with silylated nucleophiles. Organic & biomolecular chemistry [Org Biomol Chem] Journal article

 
Matsukawa S, Tsukamoto K 
TTMPP: An efficient organocatalyst in the ring-opening of aziridines with silylated nucleophiles. [Journal Article]
Org Biomol Chem 2009 Sep 21; 7(18):3792-6.


The ring-opening of N-tosylaziridines with silylated nucleophiles catalyzed by tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP) afforded the corresponding beta-functionalized sulfonamides in excellent yield under mild reaction conditions.



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