Self-assembly of star-shaped heteropoly-15-palladate(II). Dalton transactions (Cambridge, England : 2003) [Dalton Trans] Journal article | | Title | Self-assembly of star-shaped heteropoly-15-palladate(II). | | Author(s) | Izarova NV, Biboum RN, Keita B, Mifsud M, Arends IW, Jameson GB, Kortz U | | Institution | Jacobs University, School of Engineering and Science, P.O. Box 750 561, 28725, Bremen, Germany. u.kortz@jacobs-university.de. | | Source | Dalton Trans 2009 Nov 21; (43):9385-9387. | | Abstract | A novel heteropolyoxopalladate structural type has been discovered: the polyoxo-15-palladate(II) [Pd(0.4)Na(0.6) subsetPd(15)P(10)O(50)H(6.6)](12-) (Pd(15)) has been prepared in a one-pot self-assembly reaction and characterized by single-crystal XRD, elemental analysis, IR, TGA, (31)P NMR and electrochemistry; preliminary catalytic studies showed that Pd(15) is active as a catalyst in alcohol oxidation by dioxygen. | | Language | ENG | | Pub Type(s) | JOURNAL ARTICLE
| | PubMed ID | 19859589 |
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