Miura K, Inoue G, Sasagawa H, Kinoshita H, Ichikawa J, Hosomi A
Platinum-Catalyzed Nucleophilic Addition of Vinylsilanes at the beta-Position. [Journal Article]
Org Lett 2009 Nov 5; 11(21):5066-9.
In the presence of catalytic amounts of PtCl(2) and metal iodides, beta-substituted vinylsilanes reacted with aldehydes at the beta-position to give allyl silyl ethers. The Pt-catalyzed addition to aromatic aldehydes proceeded efficiently in the presence of LiI. The combined use of PtCl(2) and MnI(2) was found to be effective in addition to aliphatic aldehydes.
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