| Title | Platinum-Catalyzed Nucleophilic Addition of Vinylsilanes at the beta-Position. | | Author(s) | Miura K, Inoue G, Sasagawa H, Kinoshita H, Ichikawa J, Hosomi A | | Institution | Department of Applied Chemistry, Graduate School of Science and Engineering, Saitama University, Sakura-ku, Saitama 338-8570, Japan, and Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan. | | Source | Org Lett 2009 Nov 5; 11(21):5066-9. | | Abstract | In the presence of catalytic amounts of PtCl(2) and metal iodides, beta-substituted vinylsilanes reacted with aldehydes at the beta-position to give allyl silyl ethers. The Pt-catalyzed addition to aromatic aldehydes proceeded efficiently in the presence of LiI. The combined use of PtCl(2) and MnI(2) was found to be effective in addition to aliphatic aldehydes. | | Language | eng | | Pub Type(s) | Journal Article
| | PubMed ID | 19863155 |
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