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Chiral monodentate phosphine ligand MOP for transition-metal-catalyzed asymmetric reactions.
Acc Chem Res. 2000 Jun; 33(6):354-62.AC

Abstract

Chiral monophosphines, whose chirality is due to biaryl axial chirality, have been prepared from enantiomerically pure 2, 2'-dihydroxy-1,1'-binaphthyl and demonstrated to be highly efficient chiral ligands for transition-metal-catalyzed organic transformations, especially for reactions where chelating bisphosphine ligands cannot be used. The high efficiency is observed in palladium-catalyzed asymmetric hydrosilylation of a wide variety of olefins such as alkyl-substituted terminal olefins and in asymmetric reactions via pi-allylpalladium intermediates represented by asymmetric reduction of allylic esters with formic acid.

Authors+Show Affiliations

Hayashi T
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.

MeSH

CatalysisLigandsMetals, HeavyMolecular ConformationNaphthalenesOrganometallic CompoundsPalladiumPhosphinesSilanes

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't
Review

Language

eng

PubMed ID

10891053

Citation

Hayashi, T. "Chiral Monodentate Phosphine Ligand MOP for Transition-metal-catalyzed Asymmetric Reactions." Accounts of Chemical Research, vol. 33, no. 6, 2000, pp. 354-62.
Hayashi T. Chiral monodentate phosphine ligand MOP for transition-metal-catalyzed asymmetric reactions. Acc Chem Res. 2000;33(6):354-62.
Hayashi, T. (2000). Chiral monodentate phosphine ligand MOP for transition-metal-catalyzed asymmetric reactions. Accounts of Chemical Research, 33(6), 354-62.
Hayashi T. Chiral Monodentate Phosphine Ligand MOP for Transition-metal-catalyzed Asymmetric Reactions. Acc Chem Res. 2000;33(6):354-62. PubMed PMID: 10891053.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Chiral monodentate phosphine ligand MOP for transition-metal-catalyzed asymmetric reactions. A1 - Hayashi,T, PY - 2000/7/13/pubmed PY - 2000/9/2/medline PY - 2000/7/13/entrez SP - 354 EP - 62 JF - Accounts of chemical research JO - Acc Chem Res VL - 33 IS - 6 N2 - Chiral monophosphines, whose chirality is due to biaryl axial chirality, have been prepared from enantiomerically pure 2, 2'-dihydroxy-1,1'-binaphthyl and demonstrated to be highly efficient chiral ligands for transition-metal-catalyzed organic transformations, especially for reactions where chelating bisphosphine ligands cannot be used. The high efficiency is observed in palladium-catalyzed asymmetric hydrosilylation of a wide variety of olefins such as alkyl-substituted terminal olefins and in asymmetric reactions via pi-allylpalladium intermediates represented by asymmetric reduction of allylic esters with formic acid. SN - 0001-4842 UR - https://www.unboundmedicine.com/medline/citation/10891053/Chiral_monodentate_phosphine_ligand_MOP_for_transition_metal_catalyzed_asymmetric_reactions_ L2 - https://doi.org/10.1021/ar990080f DB - PRIME DP - Unbound Medicine ER -