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Recent progress in enantiomer separation by capillary electrochromatography.
Electrophoresis. 2000 Dec; 21(18):4136-58.E

Abstract

Enantiomer separation by electrochromatography (CEC) can be performed in three modes: (i) open-tubular capillary electrochromatography (o-CEC), in which the chiral selector is physically adsorbed coated, and thermally immobilized or covalently attached to the internal capillary wall; (ii) packed capillary electrochromatography (p-CEC), in which the capillary is either filled with chiral modified silica particles or with an achiral packing material, and a chiral selector is added to the mobile phase; and (iii) monolithic (rod)-capillary electrochromatography (rod-CEC) in which the chiral stationary phase (CSP) consists of a single piece of porous solid. We present an overview on methods and new trends in the field of electrochromatographic enantiomer separation such as CEC with either nonaqueous mobile phases or stationary phases with incorporated permanent charges, or with packing beds consisting of nonporous silica particles or particles with very small internal diameters.

Authors+Show Affiliations

Wistuba D
Institute of Organic Chemistry, University of Tübingen, Germany. dorothee.wistuba@uni-tuebingen.de
Schurig V
No affiliation info available

MeSH

Carbohydrate SequenceChromatography, High Pressure LiquidElectrophoresis, CapillaryMolecular Sequence Data

Pub Type(s)

Journal Article
Review

Language

eng

PubMed ID

11192128

Citation

Wistuba, D, and V Schurig. "Recent Progress in Enantiomer Separation By Capillary Electrochromatography." Electrophoresis, vol. 21, no. 18, 2000, pp. 4136-58.
Wistuba D, Schurig V. Recent progress in enantiomer separation by capillary electrochromatography. Electrophoresis. 2000;21(18):4136-58.
Wistuba, D., & Schurig, V. (2000). Recent progress in enantiomer separation by capillary electrochromatography. Electrophoresis, 21(18), 4136-58.
Wistuba D, Schurig V. Recent Progress in Enantiomer Separation By Capillary Electrochromatography. Electrophoresis. 2000;21(18):4136-58. PubMed PMID: 11192128.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Recent progress in enantiomer separation by capillary electrochromatography. AU - Wistuba,D, AU - Schurig,V, PY - 2001/2/24/pubmed PY - 2001/4/3/medline PY - 2001/2/24/entrez SP - 4136 EP - 58 JF - Electrophoresis JO - Electrophoresis VL - 21 IS - 18 N2 - Enantiomer separation by electrochromatography (CEC) can be performed in three modes: (i) open-tubular capillary electrochromatography (o-CEC), in which the chiral selector is physically adsorbed coated, and thermally immobilized or covalently attached to the internal capillary wall; (ii) packed capillary electrochromatography (p-CEC), in which the capillary is either filled with chiral modified silica particles or with an achiral packing material, and a chiral selector is added to the mobile phase; and (iii) monolithic (rod)-capillary electrochromatography (rod-CEC) in which the chiral stationary phase (CSP) consists of a single piece of porous solid. We present an overview on methods and new trends in the field of electrochromatographic enantiomer separation such as CEC with either nonaqueous mobile phases or stationary phases with incorporated permanent charges, or with packing beds consisting of nonporous silica particles or particles with very small internal diameters. SN - 0173-0835 UR - https://www.unboundmedicine.com/medline/citation/11192128/Recent_progress_in_enantiomer_separation_by_capillary_electrochromatography_ DB - PRIME DP - Unbound Medicine ER -