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Cycloheptadiene ring synthesis by tandem intermolecular enyne metathesis.
Org Lett. 2003 Sep 18; 5(19):3463-6.OL

Abstract

[reaction: see text] The tandem intermolecular enyne metathesis between 1-alkynes and cyclopentene is reported, providing 2-substituted 1,3-cycloheptadienes. The success of the intermolecular reaction hinges on an appropriate balance between cycloalkene ring strain and reactivity of the alkyne.

Authors+Show Affiliations

Kulkarni AA
Department of Chemistry, University at Buffalo, the State University of New York, Amherst, New York 14260, USA.
Diver ST
No affiliation info available

MeSH

AlkadienesAlkynesCatalysisCyclizationCycloheptanesCyclopentanesHydrocarbonsMethaneMolecular StructureRutheniumStereoisomerismTemperature

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't
Research Support, U.S. Gov't, P.H.S.

Language

eng

PubMed ID

12967300

Citation

Kulkarni, Amol A., and Steven T. Diver. "Cycloheptadiene Ring Synthesis By Tandem Intermolecular Enyne Metathesis." Organic Letters, vol. 5, no. 19, 2003, pp. 3463-6.
Kulkarni AA, Diver ST. Cycloheptadiene ring synthesis by tandem intermolecular enyne metathesis. Org Lett. 2003;5(19):3463-6.
Kulkarni, A. A., & Diver, S. T. (2003). Cycloheptadiene ring synthesis by tandem intermolecular enyne metathesis. Organic Letters, 5(19), 3463-6.
Kulkarni AA, Diver ST. Cycloheptadiene Ring Synthesis By Tandem Intermolecular Enyne Metathesis. Org Lett. 2003 Sep 18;5(19):3463-6. PubMed PMID: 12967300.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Cycloheptadiene ring synthesis by tandem intermolecular enyne metathesis. AU - Kulkarni,Amol A, AU - Diver,Steven T, PY - 2003/9/12/pubmed PY - 2004/2/10/medline PY - 2003/9/12/entrez SP - 3463 EP - 6 JF - Organic letters JO - Org Lett VL - 5 IS - 19 N2 - [reaction: see text] The tandem intermolecular enyne metathesis between 1-alkynes and cyclopentene is reported, providing 2-substituted 1,3-cycloheptadienes. The success of the intermolecular reaction hinges on an appropriate balance between cycloalkene ring strain and reactivity of the alkyne. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/12967300/Cycloheptadiene_ring_synthesis_by_tandem_intermolecular_enyne_metathesis_ DB - PRIME DP - Unbound Medicine ER -