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Ethylene-promoted intermolecular enyne metathesis.
Org Lett. 2003 Oct 16; 5(21):3819-22.OL

Abstract

[reaction: see text] Intermolecular enyne metathesis between functional group-rich alkynes and vinyl ethers was promoted by ethylene cometathesis. The concentration of ethylene was optimized to suppress the competing formation of butadiene through background ethylene metathesis. The role of ethylene appears to be both protective and rate enhancing.

Authors+Show Affiliations

Giessert AJ
Department of Chemistry, University at Buffalo, the State University of New York, Amherst, New York 14260, USA.
Brazis NJ
No affiliation info available
Diver ST
No affiliation info available

MeSH

AlkadienesAlkynesCatalysisEthersEthylenesModels, ChemicalMolecular StructureRuthenium CompoundsVinyl Compounds

Pub Type(s)

Journal Article
Research Support, U.S. Gov't, P.H.S.

Language

eng

PubMed ID

14535718

Citation

Giessert, Anthony J., et al. "Ethylene-promoted Intermolecular Enyne Metathesis." Organic Letters, vol. 5, no. 21, 2003, pp. 3819-22.
Giessert AJ, Brazis NJ, Diver ST. Ethylene-promoted intermolecular enyne metathesis. Org Lett. 2003;5(21):3819-22.
Giessert, A. J., Brazis, N. J., & Diver, S. T. (2003). Ethylene-promoted intermolecular enyne metathesis. Organic Letters, 5(21), 3819-22.
Giessert AJ, Brazis NJ, Diver ST. Ethylene-promoted Intermolecular Enyne Metathesis. Org Lett. 2003 Oct 16;5(21):3819-22. PubMed PMID: 14535718.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Ethylene-promoted intermolecular enyne metathesis. AU - Giessert,Anthony J, AU - Brazis,Nicholas J, AU - Diver,Steven T, PY - 2003/10/11/pubmed PY - 2004/5/15/medline PY - 2003/10/11/entrez SP - 3819 EP - 22 JF - Organic letters JO - Org Lett VL - 5 IS - 21 N2 - [reaction: see text] Intermolecular enyne metathesis between functional group-rich alkynes and vinyl ethers was promoted by ethylene cometathesis. The concentration of ethylene was optimized to suppress the competing formation of butadiene through background ethylene metathesis. The role of ethylene appears to be both protective and rate enhancing. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/14535718/Ethylene_promoted_intermolecular_enyne_metathesis_ DB - PRIME DP - Unbound Medicine ER -