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High-performance liquid chromatography (HPLC) analysis of phenolic compounds in berries with diode array and electrospray ionization mass spectrometric (MS) detection: ribes species.
J Agric Food Chem. 2003 Nov 05; 51(23):6736-44.JA

Abstract

High-performance liquid chromatography combined with diode array and electrospray ionization mass spectrometric (MS) detection was used to study phenolic compounds in berries of black, green, red, and white currants (Ribes spp.). UV-visible spectrometry was a valuable tool for the identification of the class of the phenolic compound, whereas MS and MS-MS fragmentation data were useful for further structural characterization. Distinct similarities were found in the relative distribution of conjugated forms of phenolic compounds among the four currants. Phenolic acids were found mainly as hexose esters. Flavonol glycosides and anthocyanin pigments were mainly found as 3-O-rutinosides and second as 3-O-glucosides. However, cyanidin 3-O-sambubioside and quercetin hexoside-malonate were notable phenolic compounds in red currant. Flavonol hexoside-malonates were identified and quantified in the berries of currants for the first time.

Authors+Show Affiliations

Institute of Applied Biotechnology and Food and Health Research Centre, University of Kuopio, PO Box 1627, FIN-70211 Kuopio, Finland. Kaisu.Maata@uku.fiNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

14582969

Citation

Määttä, Kaisu R., et al. "High-performance Liquid Chromatography (HPLC) Analysis of Phenolic Compounds in Berries With Diode Array and Electrospray Ionization Mass Spectrometric (MS) Detection: Ribes Species." Journal of Agricultural and Food Chemistry, vol. 51, no. 23, 2003, pp. 6736-44.
Määttä KR, Kamal-Eldin A, Törrönen AR. High-performance liquid chromatography (HPLC) analysis of phenolic compounds in berries with diode array and electrospray ionization mass spectrometric (MS) detection: ribes species. J Agric Food Chem. 2003;51(23):6736-44.
Määttä, K. R., Kamal-Eldin, A., & Törrönen, A. R. (2003). High-performance liquid chromatography (HPLC) analysis of phenolic compounds in berries with diode array and electrospray ionization mass spectrometric (MS) detection: ribes species. Journal of Agricultural and Food Chemistry, 51(23), 6736-44.
Määttä KR, Kamal-Eldin A, Törrönen AR. High-performance Liquid Chromatography (HPLC) Analysis of Phenolic Compounds in Berries With Diode Array and Electrospray Ionization Mass Spectrometric (MS) Detection: Ribes Species. J Agric Food Chem. 2003 Nov 5;51(23):6736-44. PubMed PMID: 14582969.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - High-performance liquid chromatography (HPLC) analysis of phenolic compounds in berries with diode array and electrospray ionization mass spectrometric (MS) detection: ribes species. AU - Määttä,Kaisu R, AU - Kamal-Eldin,Afaf, AU - Törrönen,A Riitta, PY - 2003/10/30/pubmed PY - 2004/1/7/medline PY - 2003/10/30/entrez SP - 6736 EP - 44 JF - Journal of agricultural and food chemistry JO - J Agric Food Chem VL - 51 IS - 23 N2 - High-performance liquid chromatography combined with diode array and electrospray ionization mass spectrometric (MS) detection was used to study phenolic compounds in berries of black, green, red, and white currants (Ribes spp.). UV-visible spectrometry was a valuable tool for the identification of the class of the phenolic compound, whereas MS and MS-MS fragmentation data were useful for further structural characterization. Distinct similarities were found in the relative distribution of conjugated forms of phenolic compounds among the four currants. Phenolic acids were found mainly as hexose esters. Flavonol glycosides and anthocyanin pigments were mainly found as 3-O-rutinosides and second as 3-O-glucosides. However, cyanidin 3-O-sambubioside and quercetin hexoside-malonate were notable phenolic compounds in red currant. Flavonol hexoside-malonates were identified and quantified in the berries of currants for the first time. SN - 0021-8561 UR - https://www.unboundmedicine.com/medline/citation/14582969/High_performance_liquid_chromatography__HPLC__analysis_of_phenolic_compounds_in_berries_with_diode_array_and_electrospray_ionization_mass_spectrometric__MS__detection:_ribes_species_ DB - PRIME DP - Unbound Medicine ER -