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Persulfate oxidation for in situ remediation of TCE. I. Activated by ferrous ion with and without a persulfate-thiosulfate redox couple.
Chemosphere. 2004 Jun; 55(9):1213-23.C

Abstract

The objective of the laboratory study is to examine the conditions under which transition metal ions (e.g., ferrous ion, Fe2+) could activate the persulfate anion (S2O8(2)-) to produce a powerful oxidant known as the sulfate free radical (SO4-*) with a standard redox potential of 2.6 V. The SO4-* is capable of destroying groundwater contaminants in situ such as trichloroethylene (TCE). Experiments using Fe2+ as an activator under various molar ratios of S2O8(2)-/Fe2+/TCE in an aqueous system indicated that partial TCE degradation occurred almost instantaneously and then the reaction stalled. Either destruction of SO4-* in the presence of excess Fe2+ or the rapid conversion of all Fe2+ to Fe3+ limited the ultimate oxidizing capability of the system. Sequential addition of Fe2+ in small increments resulted in an increased TCE removal efficiency. Therefore, it appeared that Fe2+ played an important role in generating SO4-*. An observation of oxidation-reduction potential (ORP) variations revealed that the addition of sodium thiosulfate (Na2S2O3) to the ferrous ion activated persulfate system could significantly decrease the strong oxidizing conditions. It was hypothesized that the thiosulfate induced reducing conditions might convert Fe3+ to a lower valence state of Fe2+, making the Fe2+ available to activate persulfate decomposition. The sequential addition of thiosulfate (S2O3(2)-), after the initial stalling of ferrous ion activated persulfate oxidation of TCE, resulted in an improvement in TCE removal. The ferrous ion activated persulfate-thiosulfate redox couple resulted in fairly complete TCE degradation in aqueous systems in a short time frame. In soil slurry systems, TCE degradation was slower in comparison to aqueous systems.

Authors+Show Affiliations

Department of Civil and Environmental Engineering, University of Massachusetts, One University Avenue, Lowell, MA 01854, USA. chenju_liang@uml.eduNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Comparative Study
Journal Article

Language

eng

PubMed ID

15081762

Citation

Liang, Chenju, et al. "Persulfate Oxidation for in Situ Remediation of TCE. I. Activated By Ferrous Ion With and Without a Persulfate-thiosulfate Redox Couple." Chemosphere, vol. 55, no. 9, 2004, pp. 1213-23.
Liang C, Bruell CJ, Marley MC, et al. Persulfate oxidation for in situ remediation of TCE. I. Activated by ferrous ion with and without a persulfate-thiosulfate redox couple. Chemosphere. 2004;55(9):1213-23.
Liang, C., Bruell, C. J., Marley, M. C., & Sperry, K. L. (2004). Persulfate oxidation for in situ remediation of TCE. I. Activated by ferrous ion with and without a persulfate-thiosulfate redox couple. Chemosphere, 55(9), 1213-23.
Liang C, et al. Persulfate Oxidation for in Situ Remediation of TCE. I. Activated By Ferrous Ion With and Without a Persulfate-thiosulfate Redox Couple. Chemosphere. 2004;55(9):1213-23. PubMed PMID: 15081762.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Persulfate oxidation for in situ remediation of TCE. I. Activated by ferrous ion with and without a persulfate-thiosulfate redox couple. AU - Liang,Chenju, AU - Bruell,Clifford J, AU - Marley,Michael C, AU - Sperry,Kenneth L, PY - 2003/05/16/received PY - 2003/11/13/revised PY - 2004/01/15/accepted PY - 2004/4/15/pubmed PY - 2004/6/30/medline PY - 2004/4/15/entrez SP - 1213 EP - 23 JF - Chemosphere JO - Chemosphere VL - 55 IS - 9 N2 - The objective of the laboratory study is to examine the conditions under which transition metal ions (e.g., ferrous ion, Fe2+) could activate the persulfate anion (S2O8(2)-) to produce a powerful oxidant known as the sulfate free radical (SO4-*) with a standard redox potential of 2.6 V. The SO4-* is capable of destroying groundwater contaminants in situ such as trichloroethylene (TCE). Experiments using Fe2+ as an activator under various molar ratios of S2O8(2)-/Fe2+/TCE in an aqueous system indicated that partial TCE degradation occurred almost instantaneously and then the reaction stalled. Either destruction of SO4-* in the presence of excess Fe2+ or the rapid conversion of all Fe2+ to Fe3+ limited the ultimate oxidizing capability of the system. Sequential addition of Fe2+ in small increments resulted in an increased TCE removal efficiency. Therefore, it appeared that Fe2+ played an important role in generating SO4-*. An observation of oxidation-reduction potential (ORP) variations revealed that the addition of sodium thiosulfate (Na2S2O3) to the ferrous ion activated persulfate system could significantly decrease the strong oxidizing conditions. It was hypothesized that the thiosulfate induced reducing conditions might convert Fe3+ to a lower valence state of Fe2+, making the Fe2+ available to activate persulfate decomposition. The sequential addition of thiosulfate (S2O3(2)-), after the initial stalling of ferrous ion activated persulfate oxidation of TCE, resulted in an improvement in TCE removal. The ferrous ion activated persulfate-thiosulfate redox couple resulted in fairly complete TCE degradation in aqueous systems in a short time frame. In soil slurry systems, TCE degradation was slower in comparison to aqueous systems. SN - 0045-6535 UR - https://www.unboundmedicine.com/medline/citation/15081762/Persulfate_oxidation_for_in_situ_remediation_of_TCE__I__Activated_by_ferrous_ion_with_and_without_a_persulfate_thiosulfate_redox_couple_ L2 - https://linkinghub.elsevier.com/retrieve/pii/S0045-6535(04)00066-9 DB - PRIME DP - Unbound Medicine ER -