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Ring synthesis by stereoselective, methylene-free enyne cross metathesis.
J Am Chem Soc. 2004 Jul 07; 126(26):8110-1.JA

Abstract

Tandem enyne metathesis between 1-alkynes and 1,5-cyclooctadiene or all-cis-1,4-polybutadiene resulted in a direct, one-step ring synthesis of cyclohexadienes by methylene-free metathesis. The use of methylene-free metathesis conditions provided apparent Z-selectivity in the intermolecular enyne metathesis step.

Authors+Show Affiliations

Kulkarni AA
Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, NY 14260-3000, USA.
Diver ST
No affiliation info available

MeSH

AlkadienesAlkylationAlkynesCatalysisCyclizationCyclohexanesCyclohexenesCyclooctanesHydrocarbonsMagnetic Resonance SpectroscopyMethaneMolecular StructureStereoisomerism

Pub Type(s)

Journal Article
Research Support, U.S. Gov't, P.H.S.

Language

eng

PubMed ID

15225040

Citation

Kulkarni, Amol A., and Steven T. Diver. "Ring Synthesis By Stereoselective, Methylene-free Enyne Cross Metathesis." Journal of the American Chemical Society, vol. 126, no. 26, 2004, pp. 8110-1.
Kulkarni AA, Diver ST. Ring synthesis by stereoselective, methylene-free enyne cross metathesis. J Am Chem Soc. 2004;126(26):8110-1.
Kulkarni, A. A., & Diver, S. T. (2004). Ring synthesis by stereoselective, methylene-free enyne cross metathesis. Journal of the American Chemical Society, 126(26), 8110-1.
Kulkarni AA, Diver ST. Ring Synthesis By Stereoselective, Methylene-free Enyne Cross Metathesis. J Am Chem Soc. 2004 Jul 7;126(26):8110-1. PubMed PMID: 15225040.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Ring synthesis by stereoselective, methylene-free enyne cross metathesis. AU - Kulkarni,Amol A, AU - Diver,Steven T, PY - 2004/7/1/pubmed PY - 2004/10/8/medline PY - 2004/7/1/entrez SP - 8110 EP - 1 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 126 IS - 26 N2 - Tandem enyne metathesis between 1-alkynes and 1,5-cyclooctadiene or all-cis-1,4-polybutadiene resulted in a direct, one-step ring synthesis of cyclohexadienes by methylene-free metathesis. The use of methylene-free metathesis conditions provided apparent Z-selectivity in the intermolecular enyne metathesis step. SN - 0002-7863 UR - https://www.unboundmedicine.com/medline/citation/15225040/Ring_synthesis_by_stereoselective_methylene_free_enyne_cross_metathesis_ DB - PRIME DP - Unbound Medicine ER -