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Determination of aldicarb, carbofuran and some of their main metabolites in groundwater by application of micellar electrokinetic capillary chromatography with diode-array detection and solid-phase extraction.
Pest Manag Sci. 2004 Jul; 60(7):675-9.PM

Abstract

This paper describes a UV detection method for the pesticides aldicarb and carbofuran, and some of their main metabolites, aldicarb-sulfoxide, aldicarb-sulfone and 3-hydroxy-carbofuran, in ground waters. Micellar electrokinetic chromatography (MEKC) with diode-array detection was developed for their determination at 210 nm. The experimental study was performed using sodium dodecyl sulfate (SDS) at a concentration level of 140 mM, and a buffer of borax/HCl 20 mM at pH 8 which gives the best resolution with an analysis time of less than 20 min. Different instrumental parameters such as voltage (23 kV), injection time (12 s) and temperature (25 degrees C) were optimized. The detection limits were in the range 2-7.4 microg glitre(-1) by solid-phase extraction (SPE) with a subsequent evaporation step. Groundwater spiked samples were pre-concentrated off-line with graphite carbon and subsequently analyzed by MEKC with diode-array detection yielding average recoveries between 77 and 97% (n = 4) with RSD between 2-7%.

Authors+Show Affiliations

Arráez-Román D
Department of Analytical Chemistry, Faculty of Sciences, University of Granada, Spain.
Segura-Carretero A
No affiliation info available
Cruces-Blanco C
No affiliation info available
Fernández-Gutiérrez A
No affiliation info available

MeSH

AldicarbCarbofuranChromatography, Micellar Electrokinetic CapillaryMolecular StructureUltraviolet RaysWater PurificationWater Supply

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

15260298

Citation

Arráez-Román, David, et al. "Determination of Aldicarb, Carbofuran and some of Their Main Metabolites in Groundwater By Application of Micellar Electrokinetic Capillary Chromatography With Diode-array Detection and Solid-phase Extraction." Pest Management Science, vol. 60, no. 7, 2004, pp. 675-9.
Arráez-Román D, Segura-Carretero A, Cruces-Blanco C, et al. Determination of aldicarb, carbofuran and some of their main metabolites in groundwater by application of micellar electrokinetic capillary chromatography with diode-array detection and solid-phase extraction. Pest Manag Sci. 2004;60(7):675-9.
Arráez-Román, D., Segura-Carretero, A., Cruces-Blanco, C., & Fernández-Gutiérrez, A. (2004). Determination of aldicarb, carbofuran and some of their main metabolites in groundwater by application of micellar electrokinetic capillary chromatography with diode-array detection and solid-phase extraction. Pest Management Science, 60(7), 675-9.
Arráez-Román D, et al. Determination of Aldicarb, Carbofuran and some of Their Main Metabolites in Groundwater By Application of Micellar Electrokinetic Capillary Chromatography With Diode-array Detection and Solid-phase Extraction. Pest Manag Sci. 2004;60(7):675-9. PubMed PMID: 15260298.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Determination of aldicarb, carbofuran and some of their main metabolites in groundwater by application of micellar electrokinetic capillary chromatography with diode-array detection and solid-phase extraction. AU - Arráez-Román,David, AU - Segura-Carretero,Antonio, AU - Cruces-Blanco,Carmen, AU - Fernández-Gutiérrez,Alberto, PY - 2004/7/21/pubmed PY - 2004/10/19/medline PY - 2004/7/21/entrez SP - 675 EP - 9 JF - Pest management science JO - Pest Manag Sci VL - 60 IS - 7 N2 - This paper describes a UV detection method for the pesticides aldicarb and carbofuran, and some of their main metabolites, aldicarb-sulfoxide, aldicarb-sulfone and 3-hydroxy-carbofuran, in ground waters. Micellar electrokinetic chromatography (MEKC) with diode-array detection was developed for their determination at 210 nm. The experimental study was performed using sodium dodecyl sulfate (SDS) at a concentration level of 140 mM, and a buffer of borax/HCl 20 mM at pH 8 which gives the best resolution with an analysis time of less than 20 min. Different instrumental parameters such as voltage (23 kV), injection time (12 s) and temperature (25 degrees C) were optimized. The detection limits were in the range 2-7.4 microg glitre(-1) by solid-phase extraction (SPE) with a subsequent evaporation step. Groundwater spiked samples were pre-concentrated off-line with graphite carbon and subsequently analyzed by MEKC with diode-array detection yielding average recoveries between 77 and 97% (n = 4) with RSD between 2-7%. SN - 1526-498X UR - https://www.unboundmedicine.com/medline/citation/15260298/Determination_of_aldicarb_carbofuran_and_some_of_their_main_metabolites_in_groundwater_by_application_of_micellar_electrokinetic_capillary_chromatography_with_diode_array_detection_and_solid_phase_extraction_ DB - PRIME DP - Unbound Medicine ER -