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Citrinadin A, a novel pentacyclic alkaloid from marine-derived fungus Penicillium citrinum.
Org Lett. 2004 Sep 02; 6(18):3087-9.OL

Abstract

[structure: see text] A novel pentacyclic alkaloid, citrinadin A (1), was isolated from the cultured broth of the fungus Penicillium citrinum, which was separated from a marine red alga, and the structure was elucidated by spectroscopic data. The relative stereochemistry of the pentacyclic core was assigned on the basis of NOESY data and (1)H-(1)H coupling constants, and the presence of an N,N-dimethyl-L-valine residue in 1 was determined by chiral HPLC analysis of the hydrolysate.

Authors+Show Affiliations

Tsuda M
Graduate School of Pharmaceutical Sciences, Hokkaido University, Sapporo 060-0812, Japan.
Kasai Y
No affiliation info available
Komatsu K
No affiliation info available
Sone T
No affiliation info available
Tanaka M
No affiliation info available
Mikami Y
No affiliation info available
Kobayashi J
No affiliation info available

MeSH

AlkaloidsChromatography, High Pressure LiquidIndole AlkaloidsMolecular StructureNuclear Magnetic Resonance, BiomolecularPenicilliumQuinolizinesRhodophytaValine

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

15330594

Citation

Tsuda, Masashi, et al. "Citrinadin A, a Novel Pentacyclic Alkaloid From Marine-derived Fungus Penicillium Citrinum." Organic Letters, vol. 6, no. 18, 2004, pp. 3087-9.
Tsuda M, Kasai Y, Komatsu K, et al. Citrinadin A, a novel pentacyclic alkaloid from marine-derived fungus Penicillium citrinum. Org Lett. 2004;6(18):3087-9.
Tsuda, M., Kasai, Y., Komatsu, K., Sone, T., Tanaka, M., Mikami, Y., & Kobayashi, J. (2004). Citrinadin A, a novel pentacyclic alkaloid from marine-derived fungus Penicillium citrinum. Organic Letters, 6(18), 3087-9.
Tsuda M, et al. Citrinadin A, a Novel Pentacyclic Alkaloid From Marine-derived Fungus Penicillium Citrinum. Org Lett. 2004 Sep 2;6(18):3087-9. PubMed PMID: 15330594.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Citrinadin A, a novel pentacyclic alkaloid from marine-derived fungus Penicillium citrinum. AU - Tsuda,Masashi, AU - Kasai,Yuu, AU - Komatsu,Kazusei, AU - Sone,Teruo, AU - Tanaka,Michiko, AU - Mikami,Yuzuru, AU - Kobayashi,Jun'ichi, PY - 2004/8/28/pubmed PY - 2005/9/22/medline PY - 2004/8/28/entrez SP - 3087 EP - 9 JF - Organic letters JO - Org Lett VL - 6 IS - 18 N2 - [structure: see text] A novel pentacyclic alkaloid, citrinadin A (1), was isolated from the cultured broth of the fungus Penicillium citrinum, which was separated from a marine red alga, and the structure was elucidated by spectroscopic data. The relative stereochemistry of the pentacyclic core was assigned on the basis of NOESY data and (1)H-(1)H coupling constants, and the presence of an N,N-dimethyl-L-valine residue in 1 was determined by chiral HPLC analysis of the hydrolysate. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/15330594/Citrinadin_A_a_novel_pentacyclic_alkaloid_from_marine_derived_fungus_Penicillium_citrinum_ DB - PRIME DP - Unbound Medicine ER -