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BINOL catalyzed enantioselective addition of titanium phenylacetylide to aromatic ketones.
Chem Commun (Camb). 2004 Nov 07CC

Abstract

An enantioselective addition of titanium phenylacetylide to ketones, promoted by BINOL, is described; this new enantioselective protocol gives high enantiomeric excess (up to 90% ee) with aromatic ketones using a simple procedure without pyrophoric or expensive reagents.

Authors+Show Affiliations

Dipartimento di Chimica G. Ciamician, Via Selmi 2, 40126, Bologna, Italy. piergiorgio.cozzi@unibo.itNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

15514809

Citation

Cozzi, Pier Giorgio, and Silvia Alesi. "BINOL Catalyzed Enantioselective Addition of Titanium Phenylacetylide to Aromatic Ketones." Chemical Communications (Cambridge, England), 2004, pp. 2448-9.
Cozzi PG, Alesi S. BINOL catalyzed enantioselective addition of titanium phenylacetylide to aromatic ketones. Chem Commun (Camb). 2004.
Cozzi, P. G., & Alesi, S. (2004). BINOL catalyzed enantioselective addition of titanium phenylacetylide to aromatic ketones. Chemical Communications (Cambridge, England), (21), 2448-9.
Cozzi PG, Alesi S. BINOL Catalyzed Enantioselective Addition of Titanium Phenylacetylide to Aromatic Ketones. Chem Commun (Camb). 2004 Nov 7;(21)2448-9. PubMed PMID: 15514809.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - BINOL catalyzed enantioselective addition of titanium phenylacetylide to aromatic ketones. AU - Cozzi,Pier Giorgio, AU - Alesi,Silvia, Y1 - 2004/09/21/ PY - 2004/10/30/pubmed PY - 2005/12/15/medline PY - 2004/10/30/entrez SP - 2448 EP - 9 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) IS - 21 N2 - An enantioselective addition of titanium phenylacetylide to ketones, promoted by BINOL, is described; this new enantioselective protocol gives high enantiomeric excess (up to 90% ee) with aromatic ketones using a simple procedure without pyrophoric or expensive reagents. SN - 1359-7345 UR - https://www.unboundmedicine.com/medline/citation/15514809/BINOL_catalyzed_enantioselective_addition_of_titanium_phenylacetylide_to_aromatic_ketones_ L2 - https://doi.org/10.1039/b408654f DB - PRIME DP - Unbound Medicine ER -