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Mass spectrometry in the study of anthocyanins and their derivatives: differentiation of Vitis vinifera and hybrid grapes by liquid chromatography/electrospray ionization mass spectrometry and tandem mass spectrometry.
J Mass Spectrom. 2005 Jan; 40(1):83-90.JM

Abstract

A mass spectrometric-based procedure for anthocyanin profiling was set up to distinguish authentic Vitis vinifera from hybrid red grapevine cultivars. 3-O-Monoglucoside and the related acetyl-, p-coumaryl- and caffeoyl-monoglucoside anthocyanins occurred only in Vitis vinifera, whereas 3,5-O-diglucoside and the substituted acetyl-, p-coumaryl-, feruloyl- and caffeoyl-diglucoside anthocyanins were the additional pigments in hybrid grapevines. The procedure was applied expressly to identify red grape cultivars based on the anthocyanin chemo-type determination. In particular, a red grape cultivar, having 3,5-O-diglucoside anthocyanins and a novel class of anthocyanin monoglucosides, such as cyanidin-3-O-, cyanidin-3-O-(6-O-acetyl)- and cyanidin-3-O-(6-O-p-coumaryl)pentoside, was classified as hybrid. A second vine cultivar, characterized exclusively by 3-O-monoglucoside anthocyanins, was included among the Vitis vinifera species. Anthocyanin profiling by mass spectrometry could represent the core of a chemotaxonomic procedure for distinguishing American and European grapevines based on the identification of post-synthetic anthocyanidin modification.

Authors+Show Affiliations

Mazzuca P
Dipartimento di Scienza degli Alimenti, Università degli Studi di Napoli Federico II, Via Università, I-80055 Portici, Naples, Italy.
Ferranti P
No affiliation info available
Picariello G
No affiliation info available
Chianese L
No affiliation info available
Addeo F
No affiliation info available

MeSH

AnthocyaninsChimeraChromatography, High Pressure LiquidClassificationFruitMicrochemistrySpecies SpecificitySpectrometry, Mass, Electrospray IonizationVitis

Pub Type(s)

Comparative Study
Journal Article

Language

eng

PubMed ID

15619268

Citation

Mazzuca, Pierluca, et al. "Mass Spectrometry in the Study of Anthocyanins and Their Derivatives: Differentiation of Vitis Vinifera and Hybrid Grapes By Liquid Chromatography/electrospray Ionization Mass Spectrometry and Tandem Mass Spectrometry." Journal of Mass Spectrometry : JMS, vol. 40, no. 1, 2005, pp. 83-90.
Mazzuca P, Ferranti P, Picariello G, et al. Mass spectrometry in the study of anthocyanins and their derivatives: differentiation of Vitis vinifera and hybrid grapes by liquid chromatography/electrospray ionization mass spectrometry and tandem mass spectrometry. J Mass Spectrom. 2005;40(1):83-90.
Mazzuca, P., Ferranti, P., Picariello, G., Chianese, L., & Addeo, F. (2005). Mass spectrometry in the study of anthocyanins and their derivatives: differentiation of Vitis vinifera and hybrid grapes by liquid chromatography/electrospray ionization mass spectrometry and tandem mass spectrometry. Journal of Mass Spectrometry : JMS, 40(1), 83-90.
Mazzuca P, et al. Mass Spectrometry in the Study of Anthocyanins and Their Derivatives: Differentiation of Vitis Vinifera and Hybrid Grapes By Liquid Chromatography/electrospray Ionization Mass Spectrometry and Tandem Mass Spectrometry. J Mass Spectrom. 2005;40(1):83-90. PubMed PMID: 15619268.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Mass spectrometry in the study of anthocyanins and their derivatives: differentiation of Vitis vinifera and hybrid grapes by liquid chromatography/electrospray ionization mass spectrometry and tandem mass spectrometry. AU - Mazzuca,Pierluca, AU - Ferranti,Pasquale, AU - Picariello,Gianluca, AU - Chianese,Lina, AU - Addeo,Francesco, PY - 2004/12/25/pubmed PY - 2005/4/19/medline PY - 2004/12/25/entrez SP - 83 EP - 90 JF - Journal of mass spectrometry : JMS JO - J Mass Spectrom VL - 40 IS - 1 N2 - A mass spectrometric-based procedure for anthocyanin profiling was set up to distinguish authentic Vitis vinifera from hybrid red grapevine cultivars. 3-O-Monoglucoside and the related acetyl-, p-coumaryl- and caffeoyl-monoglucoside anthocyanins occurred only in Vitis vinifera, whereas 3,5-O-diglucoside and the substituted acetyl-, p-coumaryl-, feruloyl- and caffeoyl-diglucoside anthocyanins were the additional pigments in hybrid grapevines. The procedure was applied expressly to identify red grape cultivars based on the anthocyanin chemo-type determination. In particular, a red grape cultivar, having 3,5-O-diglucoside anthocyanins and a novel class of anthocyanin monoglucosides, such as cyanidin-3-O-, cyanidin-3-O-(6-O-acetyl)- and cyanidin-3-O-(6-O-p-coumaryl)pentoside, was classified as hybrid. A second vine cultivar, characterized exclusively by 3-O-monoglucoside anthocyanins, was included among the Vitis vinifera species. Anthocyanin profiling by mass spectrometry could represent the core of a chemotaxonomic procedure for distinguishing American and European grapevines based on the identification of post-synthetic anthocyanidin modification. SN - 1076-5174 UR - https://www.unboundmedicine.com/medline/citation/15619268/Mass_spectrometry_in_the_study_of_anthocyanins_and_their_derivatives:_differentiation_of_Vitis_vinifera_and_hybrid_grapes_by_liquid_chromatography/electrospray_ionization_mass_spectrometry_and_tandem_mass_spectrometry_ DB - PRIME DP - Unbound Medicine ER -