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Highly enantioselective allylation of aldehydes catalyzed by indium(III)-PYBOX complex.
Org Lett. 2005 Jan 06; 7(1):159-61.OL

Abstract

A chiral indium(III)-PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, alpha,beta-unsaturated, and aliphatic aldehydes resulted in good yields and high enantioselectivities (up to 94% ee).

Authors+Show Affiliations

Department of Chemistry, National Unviversity of Singapore, 3 Science Drive 3, Singapore 117543.No affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

15625002

Citation

Lu, Jun, et al. "Highly Enantioselective Allylation of Aldehydes Catalyzed By indium(III)-PYBOX Complex." Organic Letters, vol. 7, no. 1, 2005, pp. 159-61.
Lu J, Ji SJ, Teo YC, et al. Highly enantioselective allylation of aldehydes catalyzed by indium(III)-PYBOX complex. Org Lett. 2005;7(1):159-61.
Lu, J., Ji, S. J., Teo, Y. C., & Loh, T. P. (2005). Highly enantioselective allylation of aldehydes catalyzed by indium(III)-PYBOX complex. Organic Letters, 7(1), 159-61.
Lu J, et al. Highly Enantioselective Allylation of Aldehydes Catalyzed By indium(III)-PYBOX Complex. Org Lett. 2005 Jan 6;7(1):159-61. PubMed PMID: 15625002.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Highly enantioselective allylation of aldehydes catalyzed by indium(III)-PYBOX complex. AU - Lu,Jun, AU - Ji,Shun-Jun, AU - Teo,Yong-Chua, AU - Loh,Teck-Peng, PY - 2004/12/31/pubmed PY - 2006/6/10/medline PY - 2004/12/31/entrez SP - 159 EP - 61 JF - Organic letters JO - Org Lett VL - 7 IS - 1 N2 - A chiral indium(III)-PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, alpha,beta-unsaturated, and aliphatic aldehydes resulted in good yields and high enantioselectivities (up to 94% ee). SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/15625002/Highly_enantioselective_allylation_of_aldehydes_catalyzed_by_indium_III__PYBOX_complex_ L2 - https://doi.org/10.1021/ol047711c DB - PRIME DP - Unbound Medicine ER -