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Highly enantioselective allylation of aldehydes catalyzed by indium(III)-PYBOX complex.
Org Lett. 2005 Jan 06; 7(1):159-61.OL

Abstract

A chiral indium(III)-PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, alpha,beta-unsaturated, and aliphatic aldehydes resulted in good yields and high enantioselectivities (up to 94% ee).

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Authors+Show Affiliations

Lu J
Department of Chemistry, National Unviversity of Singapore, 3 Science Drive 3, Singapore 117543.
Ji SJ
No affiliation info available
Teo YC
No affiliation info available
Loh TP
No affiliation info available

MeSH

AldehydesAllyl CompoundsCatalysisIndiumOrganometallic CompoundsOxazolesPyridinesStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

15625002

Citation

Lu, Jun, et al. "Highly Enantioselective Allylation of Aldehydes Catalyzed By indium(III)-PYBOX Complex." Organic Letters, vol. 7, no. 1, 2005, pp. 159-61.
Lu J, Ji SJ, Teo YC, et al. Highly enantioselective allylation of aldehydes catalyzed by indium(III)-PYBOX complex. Org Lett. 2005;7(1):159-61.
Lu, J., Ji, S. J., Teo, Y. C., & Loh, T. P. (2005). Highly enantioselective allylation of aldehydes catalyzed by indium(III)-PYBOX complex. Organic Letters, 7(1), 159-61.
Lu J, et al. Highly Enantioselective Allylation of Aldehydes Catalyzed By indium(III)-PYBOX Complex. Org Lett. 2005 Jan 6;7(1):159-61. PubMed PMID: 15625002.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Highly enantioselective allylation of aldehydes catalyzed by indium(III)-PYBOX complex. AU - Lu,Jun, AU - Ji,Shun-Jun, AU - Teo,Yong-Chua, AU - Loh,Teck-Peng, PY - 2004/12/31/pubmed PY - 2006/6/10/medline PY - 2004/12/31/entrez SP - 159 EP - 61 JF - Organic letters JO - Org Lett VL - 7 IS - 1 N2 - A chiral indium(III)-PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, alpha,beta-unsaturated, and aliphatic aldehydes resulted in good yields and high enantioselectivities (up to 94% ee). SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/15625002/Highly_enantioselective_allylation_of_aldehydes_catalyzed_by_indium_III__PYBOX_complex_ L2 - https://doi.org/10.1021/ol047711c DB - PRIME DP - Unbound Medicine ER -