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Cross enyne metathesis of para-substituted styrenes: a kinetic study of enyne metathesis.
Org Lett. 2005 Jan 20; 7(2):351-4.OL

Abstract

[Reaction: see text] The intermolecular enyne metathesis between alkynes and styrene derivatives was developed to study electronic effects in enyne metathesis. A Hammett plot for the overall reaction, catalyst initiation and vinyl carbene turnover was determined with the second generation Grubbs ruthenium carbene catalyst.

Authors+Show Affiliations

Giessert AJ
Department of Chemistry, University at Buffalo, The State University of New York, Amherst, New York 14260, USA.
Diver ST
No affiliation info available

MeSH

AlkynesCatalysisHydrocarbonsKineticsMethaneMolecular StructureRutheniumStyrenes

Pub Type(s)

Journal Article
Research Support, N.I.H., Extramural
Research Support, U.S. Gov't, Non-P.H.S.

Language

eng

PubMed ID

15646995

Citation

Giessert, Anthony J., and Steven T. Diver. "Cross Enyne Metathesis of Para-substituted Styrenes: a Kinetic Study of Enyne Metathesis." Organic Letters, vol. 7, no. 2, 2005, pp. 351-4.
Giessert AJ, Diver ST. Cross enyne metathesis of para-substituted styrenes: a kinetic study of enyne metathesis. Org Lett. 2005;7(2):351-4.
Giessert, A. J., & Diver, S. T. (2005). Cross enyne metathesis of para-substituted styrenes: a kinetic study of enyne metathesis. Organic Letters, 7(2), 351-4.
Giessert AJ, Diver ST. Cross Enyne Metathesis of Para-substituted Styrenes: a Kinetic Study of Enyne Metathesis. Org Lett. 2005 Jan 20;7(2):351-4. PubMed PMID: 15646995.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Cross enyne metathesis of para-substituted styrenes: a kinetic study of enyne metathesis. AU - Giessert,Anthony J, AU - Diver,Steven T, PY - 2005/1/14/pubmed PY - 2006/7/6/medline PY - 2005/1/14/entrez SP - 351 EP - 4 JF - Organic letters JO - Org Lett VL - 7 IS - 2 N2 - [Reaction: see text] The intermolecular enyne metathesis between alkynes and styrene derivatives was developed to study electronic effects in enyne metathesis. A Hammett plot for the overall reaction, catalyst initiation and vinyl carbene turnover was determined with the second generation Grubbs ruthenium carbene catalyst. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/15646995/Cross_enyne_metathesis_of_para_substituted_styrenes:_a_kinetic_study_of_enyne_metathesis_ DB - PRIME DP - Unbound Medicine ER -