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A fluorous chiral dirhodium(II) complex as a recyclable asymmetric catalyst.
Org Lett. 2005 Apr 28; 7(9):1841-4.OL

Abstract

[reaction: see text] The chiral fluorous complex tetrakis-dirhodium(II)-(S)-N-(n-perfluorooctylsulfonyl)prolinate has been prepared and used as a catalyst in homogeneous or fluorous biphasic fashion. The catalyst displays good chemo- and enantioselectivity in intermolecular cyclopropanation and C-H bond activation reactions. The catalyst can be simply and thoroughly separated from the reaction mixture and is recyclable.

Authors+Show Affiliations

Dipartimento di Scienze Chimiche, Università di Padova, via Marzolo 1, I-35131 Padova, Italy. andrea.biffis@unipd.itNo affiliation info availableNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

15844920

Citation

Biffis, Andrea, et al. "A Fluorous Chiral dirhodium(II) Complex as a Recyclable Asymmetric Catalyst." Organic Letters, vol. 7, no. 9, 2005, pp. 1841-4.
Biffis A, Braga M, Cadamuro S, et al. A fluorous chiral dirhodium(II) complex as a recyclable asymmetric catalyst. Org Lett. 2005;7(9):1841-4.
Biffis, A., Braga, M., Cadamuro, S., Tubaro, C., & Basato, M. (2005). A fluorous chiral dirhodium(II) complex as a recyclable asymmetric catalyst. Organic Letters, 7(9), 1841-4.
Biffis A, et al. A Fluorous Chiral dirhodium(II) Complex as a Recyclable Asymmetric Catalyst. Org Lett. 2005 Apr 28;7(9):1841-4. PubMed PMID: 15844920.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - A fluorous chiral dirhodium(II) complex as a recyclable asymmetric catalyst. AU - Biffis,Andrea, AU - Braga,Mirko, AU - Cadamuro,Sara, AU - Tubaro,Cristina, AU - Basato,Marino, PY - 2005/4/23/pubmed PY - 2006/2/10/medline PY - 2005/4/23/entrez SP - 1841 EP - 4 JF - Organic letters JO - Org Lett VL - 7 IS - 9 N2 - [reaction: see text] The chiral fluorous complex tetrakis-dirhodium(II)-(S)-N-(n-perfluorooctylsulfonyl)prolinate has been prepared and used as a catalyst in homogeneous or fluorous biphasic fashion. The catalyst displays good chemo- and enantioselectivity in intermolecular cyclopropanation and C-H bond activation reactions. The catalyst can be simply and thoroughly separated from the reaction mixture and is recyclable. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/15844920/A_fluorous_chiral_dirhodium_II__complex_as_a_recyclable_asymmetric_catalyst_ L2 - https://doi.org/10.1021/ol050486u DB - PRIME DP - Unbound Medicine ER -