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Boron-directed regio- and stereoselective enyne cross metathesis: efficient synthesis of vinyl boronate containing 1,3-dienes.
Org Lett. 2005 Apr 28; 7(9):1865-8.OL

Abstract

[reaction: see text] Regio- and stereoselective enyne cross metathesis reactions between borylated alkynes and terminal alkenes were realized to provide a variety of functionalized vinyl boronates. High chemical yield and regioselectivity was achieved irrespective of substituents on the alkyne and alkene counterparts, whereas Z/E-selectivity was found to be dependent upon the substituents both on the alkyne and alkene.

Authors+Show Affiliations

Kim M
Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706, USA.
Lee D
No affiliation info available

MeSH

AlkenesBoronic AcidsCombinatorial Chemistry TechniquesMolecular StructureStereoisomerismVinyl Compounds

Pub Type(s)

Journal Article
Research Support, N.I.H., Extramural
Research Support, U.S. Gov't, Non-P.H.S.
Research Support, U.S. Gov't, P.H.S.

Language

eng

PubMed ID

15844926

Citation

Kim, Mansuk, and Daesung Lee. "Boron-directed Regio- and Stereoselective Enyne Cross Metathesis: Efficient Synthesis of Vinyl Boronate Containing 1,3-dienes." Organic Letters, vol. 7, no. 9, 2005, pp. 1865-8.
Kim M, Lee D. Boron-directed regio- and stereoselective enyne cross metathesis: efficient synthesis of vinyl boronate containing 1,3-dienes. Org Lett. 2005;7(9):1865-8.
Kim, M., & Lee, D. (2005). Boron-directed regio- and stereoselective enyne cross metathesis: efficient synthesis of vinyl boronate containing 1,3-dienes. Organic Letters, 7(9), 1865-8.
Kim M, Lee D. Boron-directed Regio- and Stereoselective Enyne Cross Metathesis: Efficient Synthesis of Vinyl Boronate Containing 1,3-dienes. Org Lett. 2005 Apr 28;7(9):1865-8. PubMed PMID: 15844926.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Boron-directed regio- and stereoselective enyne cross metathesis: efficient synthesis of vinyl boronate containing 1,3-dienes. AU - Kim,Mansuk, AU - Lee,Daesung, PY - 2005/4/23/pubmed PY - 2006/2/10/medline PY - 2005/4/23/entrez SP - 1865 EP - 8 JF - Organic letters JO - Org Lett VL - 7 IS - 9 N2 - [reaction: see text] Regio- and stereoselective enyne cross metathesis reactions between borylated alkynes and terminal alkenes were realized to provide a variety of functionalized vinyl boronates. High chemical yield and regioselectivity was achieved irrespective of substituents on the alkyne and alkene counterparts, whereas Z/E-selectivity was found to be dependent upon the substituents both on the alkyne and alkene. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/15844926/Boron_directed_regio__and_stereoselective_enyne_cross_metathesis:_efficient_synthesis_of_vinyl_boronate_containing_13_dienes_ DB - PRIME DP - Unbound Medicine ER -