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Synthesis of polycyclic aromatics and heteroaromatics via electrophilic cyclization.
J Org Chem. 2005 Apr 29; 70(9):3511-7.JO

Abstract

[reaction: see text] A variety of substituted polycyclic aromatics are readily prepared in good to excellent yields under very mild reaction conditions by the reaction of 2-(1-alkynyl)biphenyls with ICl, I(2), NBS, and p-O(2)NC(6)H(4)SCl. This methodology readily accommodates various functional groups and has been successfully extended to systems containing a variety of polycyclic and heterocyclic rings.

Authors+Show Affiliations

Yao T
Department of Chemistry, Iowa State University, Ames, Iowa 50011, USA.
Campo MA
No affiliation info available
Larock RC
No affiliation info available

MeSH

CatalysisCyclizationHeterocyclic Compounds, 4 or More RingsIndicators and ReagentsMolecular StructurePalladiumPolycyclic Aromatic Hydrocarbons

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't
Research Support, U.S. Gov't, Non-P.H.S.
Research Support, U.S. Gov't, P.H.S.

Language

eng

PubMed ID

15844984

Citation

Yao, Tuanli, et al. "Synthesis of Polycyclic Aromatics and Heteroaromatics Via Electrophilic Cyclization." The Journal of Organic Chemistry, vol. 70, no. 9, 2005, pp. 3511-7.
Yao T, Campo MA, Larock RC. Synthesis of polycyclic aromatics and heteroaromatics via electrophilic cyclization. J Org Chem. 2005;70(9):3511-7.
Yao, T., Campo, M. A., & Larock, R. C. (2005). Synthesis of polycyclic aromatics and heteroaromatics via electrophilic cyclization. The Journal of Organic Chemistry, 70(9), 3511-7.
Yao T, Campo MA, Larock RC. Synthesis of Polycyclic Aromatics and Heteroaromatics Via Electrophilic Cyclization. J Org Chem. 2005 Apr 29;70(9):3511-7. PubMed PMID: 15844984.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Synthesis of polycyclic aromatics and heteroaromatics via electrophilic cyclization. AU - Yao,Tuanli, AU - Campo,Marino A, AU - Larock,Richard C, PY - 2005/4/23/pubmed PY - 2005/5/25/medline PY - 2005/4/23/entrez SP - 3511 EP - 7 JF - The Journal of organic chemistry JO - J Org Chem VL - 70 IS - 9 N2 - [reaction: see text] A variety of substituted polycyclic aromatics are readily prepared in good to excellent yields under very mild reaction conditions by the reaction of 2-(1-alkynyl)biphenyls with ICl, I(2), NBS, and p-O(2)NC(6)H(4)SCl. This methodology readily accommodates various functional groups and has been successfully extended to systems containing a variety of polycyclic and heterocyclic rings. SN - 0022-3263 UR - https://www.unboundmedicine.com/medline/citation/15844984/Synthesis_of_polycyclic_aromatics_and_heteroaromatics_via_electrophilic_cyclization_ DB - PRIME DP - Unbound Medicine ER -