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Enantioselective allylation of aldehydes catalyzed by chiral indium(III) complexes immobilized in ionic liquids.
Chem Commun (Camb). 2005 May 14CC

Abstract

In the presence of chiral catalytic complexes prepared from In(OTf)3 and chiral PYBOX ligands, allytributylstannane reacted with aldehydes in ionic liquids to afford the corresponding homoallylic alcohols in high enantioselectivities (86-94% ee) and good yields (68-89%); the chiral catalysts immobilized in ionic liquids could be reused with comparable enantioselectivities and yields.

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Authors+Show Affiliations

Lu J
Key Lab. of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering of Suzhou University, Suzhou, 215006, China. shunjun@suda.edu.cn
Ji SJ
No affiliation info available
Loh TP
No affiliation info available

MeSH

AlcoholsAldehydesAlkylationCatalysisIndiumIonic LiquidsMolecular StructureOrganometallic CompoundsOrganotin CompoundsStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

15877123

Citation

Lu, Jun, et al. "Enantioselective Allylation of Aldehydes Catalyzed By Chiral indium(III) Complexes Immobilized in Ionic Liquids." Chemical Communications (Cambridge, England), 2005, pp. 2345-7.
Lu J, Ji SJ, Loh TP. Enantioselective allylation of aldehydes catalyzed by chiral indium(III) complexes immobilized in ionic liquids. Chem Commun (Camb). 2005.
Lu, J., Ji, S. J., & Loh, T. P. (2005). Enantioselective allylation of aldehydes catalyzed by chiral indium(III) complexes immobilized in ionic liquids. Chemical Communications (Cambridge, England), (18), 2345-7.
Lu J, Ji SJ, Loh TP. Enantioselective Allylation of Aldehydes Catalyzed By Chiral indium(III) Complexes Immobilized in Ionic Liquids. Chem Commun (Camb). 2005 May 14;(18)2345-7. PubMed PMID: 15877123.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Enantioselective allylation of aldehydes catalyzed by chiral indium(III) complexes immobilized in ionic liquids. AU - Lu,Jun, AU - Ji,Shun-Jun, AU - Loh,Teck-Peng, Y1 - 2005/03/15/ PY - 2005/5/7/pubmed PY - 2007/3/14/medline PY - 2005/5/7/entrez SP - 2345 EP - 7 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) IS - 18 N2 - In the presence of chiral catalytic complexes prepared from In(OTf)3 and chiral PYBOX ligands, allytributylstannane reacted with aldehydes in ionic liquids to afford the corresponding homoallylic alcohols in high enantioselectivities (86-94% ee) and good yields (68-89%); the chiral catalysts immobilized in ionic liquids could be reused with comparable enantioselectivities and yields. SN - 1359-7345 UR - https://www.unboundmedicine.com/medline/citation/15877123/Enantioselective_allylation_of_aldehydes_catalyzed_by_chiral_indium_III__complexes_immobilized_in_ionic_liquids_ L2 - https://doi.org/10.1039/b500086f DB - PRIME DP - Unbound Medicine ER -