Prebiotic carbohydrate synthesis: zinc-proline catalyzes direct aqueous aldol reactions of alpha-hydroxy aldehydes and ketones.
Org Biomol Chem. 2005 May 21; 3(10):1850-5.OB

Abstract

Zn-proline catalyzed aldolisation of glycoladehyde gave mainly tetroses whereas in the cross-aldolisation of glycoladehyde and rac-glyceraldehyde, pentoses accounted for 60% of the sugars formed with 20% of ribose.

Authors+Show Affiliations

Kofoed J

Department of Chemistry and Biochemistry, University of Berne, Freiestrasse 3, 3012, Berne, Switzerland.

Reymond JL

No affiliation info available

Darbre T

No affiliation info available

MeSH

AcetylationAldehydesCarbohydratesCatalysisChromatography, GasKetonesProlineZinc

Pub Type(s)

Journal Article

Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

15889167

Citation

Kofoed, Jacob, et al. "Prebiotic Carbohydrate Synthesis: Zinc-proline Catalyzes Direct Aqueous Aldol Reactions of Alpha-hydroxy Aldehydes and Ketones." Organic & Biomolecular Chemistry, vol. 3, no. 10, 2005, pp. 1850-5.

Kofoed J, Reymond JL, Darbre T. Prebiotic carbohydrate synthesis: zinc-proline catalyzes direct aqueous aldol reactions of alpha-hydroxy aldehydes and ketones. Org Biomol Chem. 2005;3(10):1850-5.

Kofoed, J., Reymond, J. L., & Darbre, T. (2005). Prebiotic carbohydrate synthesis: zinc-proline catalyzes direct aqueous aldol reactions of alpha-hydroxy aldehydes and ketones. Organic & Biomolecular Chemistry, 3(10), 1850-5.

Kofoed J, Reymond JL, Darbre T. Prebiotic Carbohydrate Synthesis: Zinc-proline Catalyzes Direct Aqueous Aldol Reactions of Alpha-hydroxy Aldehydes and Ketones. Org Biomol Chem. 2005 May 21;3(10):1850-5. PubMed PMID: 15889167.

* Article titles in AMA citation format should be in sentence-case

TY - JOUR T1 - Prebiotic carbohydrate synthesis: zinc-proline catalyzes direct aqueous aldol reactions of alpha-hydroxy aldehydes and ketones. AU - Kofoed,Jacob, AU - Reymond,Jean-Louis, AU - Darbre,Tamis, Y1 - 2005/04/14/ PY - 2005/5/13/pubmed PY - 2006/7/18/medline PY - 2005/5/13/entrez SP - 1850 EP - 5 JF - Organic & biomolecular chemistry JO - Org Biomol Chem VL - 3 IS - 10 N2 - Zn-proline catalyzed aldolisation of glycoladehyde gave mainly tetroses whereas in the cross-aldolisation of glycoladehyde and rac-glyceraldehyde, pentoses accounted for 60% of the sugars formed with 20% of ribose. SN - 1477-0520 UR - https://www.unboundmedicine.com/medline/citation/15889167/Prebiotic_carbohydrate_synthesis:_zinc_proline_catalyzes_direct_aqueous_aldol_reactions_of_alpha_hydroxy_aldehydes_and_ketones_ DB - PRIME DP - Unbound Medicine ER -

Tags

Prebiotic carbohydrate synthesis: zinc-proline catalyzes direct aqueous aldol reactions of alpha-hydroxy aldehydes and ketones.Org Biomol Chem. 2005 May 21; 3(10):1850-5.OB