Rhodium-catalyzed arylation using arylboron compounds: efficient coupling with aryl halides and unexpected multiple arylation of benzonitrile.Org Lett. 2005 May 26; 7(11):2229-31.OL
Abstract
[reaction: see text]. The Suzuki-Miyaura-type cross-coupling of arylboron compounds with aryl halides proceeds efficiently in the presence of a rhodium-based catalyst system to produce the corresponding biaryls. Furthermore, it has unexpectedly been observed that the treatment with benzonitrile under similar conditions brings about its multiple arylation, in which nucleophilic arylation on the cyano group and subsequent ortho arylation via C-H bond cleavage are involved.
Pub Type(s)
Journal Article
Language
eng
PubMed ID
15901176
Citation
Ueura, Kenji, et al. "Rhodium-catalyzed Arylation Using Arylboron Compounds: Efficient Coupling With Aryl Halides and Unexpected Multiple Arylation of Benzonitrile." Organic Letters, vol. 7, no. 11, 2005, pp. 2229-31.
Ueura K, Satoh T, Miura M. Rhodium-catalyzed arylation using arylboron compounds: efficient coupling with aryl halides and unexpected multiple arylation of benzonitrile. Org Lett. 2005;7(11):2229-31.
Ueura, K., Satoh, T., & Miura, M. (2005). Rhodium-catalyzed arylation using arylboron compounds: efficient coupling with aryl halides and unexpected multiple arylation of benzonitrile. Organic Letters, 7(11), 2229-31.
Ueura K, Satoh T, Miura M. Rhodium-catalyzed Arylation Using Arylboron Compounds: Efficient Coupling With Aryl Halides and Unexpected Multiple Arylation of Benzonitrile. Org Lett. 2005 May 26;7(11):2229-31. PubMed PMID: 15901176.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR
T1 - Rhodium-catalyzed arylation using arylboron compounds: efficient coupling with aryl halides and unexpected multiple arylation of benzonitrile.
AU - Ueura,Kenji,
AU - Satoh,Tetsuya,
AU - Miura,Masahiro,
PY - 2005/5/20/pubmed
PY - 2005/5/20/medline
PY - 2005/5/20/entrez
SP - 2229
EP - 31
JF - Organic letters
JO - Org Lett
VL - 7
IS - 11
N2 - [reaction: see text]. The Suzuki-Miyaura-type cross-coupling of arylboron compounds with aryl halides proceeds efficiently in the presence of a rhodium-based catalyst system to produce the corresponding biaryls. Furthermore, it has unexpectedly been observed that the treatment with benzonitrile under similar conditions brings about its multiple arylation, in which nucleophilic arylation on the cyano group and subsequent ortho arylation via C-H bond cleavage are involved.
SN - 1523-7060
UR - https://www.unboundmedicine.com/medline/citation/15901176/Rhodium_catalyzed_arylation_using_arylboron_compounds:_efficient_coupling_with_aryl_halides_and_unexpected_multiple_arylation_of_benzonitrile_
DB - PRIME
DP - Unbound Medicine
ER -
