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Rh(I)-catalyzed CO gas-free cyclohydrocarbonylation of alkynes with formaldehyde to alpha,beta-butenolides.
Chem Commun (Camb). 2005 Jul 14CC

Abstract

The rhodium(I)-catalyzed reaction of alkynes with formaldehyde proceeds via the double incorporation of a carbonyl moiety from formaldehyde, resulting in a CO gas-free cyclohydrocarbonylation leading to alpha,beta-butenolides.

Authors+Show Affiliations

Fuji K
Graduate School of Materials Science, Nara Institute of Science and Technology, Takayama, Ikoma, Nara 630-0192, Japan.
Morimoto T
No affiliation info available
Tsutsumi K
No affiliation info available
Kakiuchi K
No affiliation info available

MeSH

4-ButyrolactoneAlkynesCarbon MonoxideCatalysisCyclizationFormaldehydeMolecular StructureRhodiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

15983652

Citation

Fuji, Koji, et al. "Rh(I)-catalyzed CO Gas-free Cyclohydrocarbonylation of Alkynes With Formaldehyde to Alpha,beta-butenolides." Chemical Communications (Cambridge, England), 2005, pp. 3295-7.
Fuji K, Morimoto T, Tsutsumi K, et al. Rh(I)-catalyzed CO gas-free cyclohydrocarbonylation of alkynes with formaldehyde to alpha,beta-butenolides. Chem Commun (Camb). 2005.
Fuji, K., Morimoto, T., Tsutsumi, K., & Kakiuchi, K. (2005). Rh(I)-catalyzed CO gas-free cyclohydrocarbonylation of alkynes with formaldehyde to alpha,beta-butenolides. Chemical Communications (Cambridge, England), (26), 3295-7.
Fuji K, et al. Rh(I)-catalyzed CO Gas-free Cyclohydrocarbonylation of Alkynes With Formaldehyde to Alpha,beta-butenolides. Chem Commun (Camb). 2005 Jul 14;(26)3295-7. PubMed PMID: 15983652.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rh(I)-catalyzed CO gas-free cyclohydrocarbonylation of alkynes with formaldehyde to alpha,beta-butenolides. AU - Fuji,Koji, AU - Morimoto,Tsumoru, AU - Tsutsumi,Ken, AU - Kakiuchi,Kiyomi, Y1 - 2005/06/01/ PY - 2005/6/29/pubmed PY - 2007/7/3/medline PY - 2005/6/29/entrez SP - 3295 EP - 7 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) IS - 26 N2 - The rhodium(I)-catalyzed reaction of alkynes with formaldehyde proceeds via the double incorporation of a carbonyl moiety from formaldehyde, resulting in a CO gas-free cyclohydrocarbonylation leading to alpha,beta-butenolides. SN - 1359-7345 UR - https://www.unboundmedicine.com/medline/citation/15983652/Rh_I__catalyzed_CO_gas_free_cyclohydrocarbonylation_of_alkynes_with_formaldehyde_to_alphabeta_butenolides_ DB - PRIME DP - Unbound Medicine ER -