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Preferential oxidative addition in palladium(0)-catalyzed suzuki cross-coupling reactions of dihaloarenes with arylboronic acids.
J Am Chem Soc. 2005 Jul 20; 127(28):10006-7.JA

Abstract

The study of Pd(0)-/t-Bu3P system as a powerful catalyst for the cross-coupling of n,m-dihaloarenes with 1 equiv of arylboronic acids is described. Our work demonstrated that the fate of the regenerated Pd(0) catalyst can be controlled when the appropriate ligand is employed. The results described here may lead to the development of new, efficient processes to conjugate polymers with controlled length which are potentially useful in molecular electronics.

Authors+Show Affiliations

Dong CG
Department of Chemistry, College of Staten Island and the Graduate Center of the City University of New York, Staten Island, New York 10314, USA.
Hu QS
No affiliation info available

MeSH

Benzene DerivativesBoronic AcidsCatalysisHydrocarbons, HalogenatedMolecular StructureOxidation-ReductionPalladiumPolymers

Pub Type(s)

Journal Article
Research Support, N.I.H., Extramural
Research Support, Non-U.S. Gov't
Research Support, U.S. Gov't, P.H.S.

Language

eng

PubMed ID

16011357

Citation

Dong, Cheng-Guo, and Qiao-Sheng Hu. "Preferential Oxidative Addition in Palladium(0)-catalyzed Suzuki Cross-coupling Reactions of Dihaloarenes With Arylboronic Acids." Journal of the American Chemical Society, vol. 127, no. 28, 2005, pp. 10006-7.
Dong CG, Hu QS. Preferential oxidative addition in palladium(0)-catalyzed suzuki cross-coupling reactions of dihaloarenes with arylboronic acids. J Am Chem Soc. 2005;127(28):10006-7.
Dong, C. G., & Hu, Q. S. (2005). Preferential oxidative addition in palladium(0)-catalyzed suzuki cross-coupling reactions of dihaloarenes with arylboronic acids. Journal of the American Chemical Society, 127(28), 10006-7.
Dong CG, Hu QS. Preferential Oxidative Addition in Palladium(0)-catalyzed Suzuki Cross-coupling Reactions of Dihaloarenes With Arylboronic Acids. J Am Chem Soc. 2005 Jul 20;127(28):10006-7. PubMed PMID: 16011357.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Preferential oxidative addition in palladium(0)-catalyzed suzuki cross-coupling reactions of dihaloarenes with arylboronic acids. AU - Dong,Cheng-Guo, AU - Hu,Qiao-Sheng, PY - 2005/7/14/pubmed PY - 2005/11/1/medline PY - 2005/7/14/entrez SP - 10006 EP - 7 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 127 IS - 28 N2 - The study of Pd(0)-/t-Bu3P system as a powerful catalyst for the cross-coupling of n,m-dihaloarenes with 1 equiv of arylboronic acids is described. Our work demonstrated that the fate of the regenerated Pd(0) catalyst can be controlled when the appropriate ligand is employed. The results described here may lead to the development of new, efficient processes to conjugate polymers with controlled length which are potentially useful in molecular electronics. SN - 0002-7863 UR - https://www.unboundmedicine.com/medline/citation/16011357/Preferential_oxidative_addition_in_palladium_0__catalyzed_suzuki_cross_coupling_reactions_of_dihaloarenes_with_arylboronic_acids_ DB - PRIME DP - Unbound Medicine ER -