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Development of new cycloaddition reactions based on the unique reactivity of unsaturated hydrocarbons.
Chem Pharm Bull (Tokyo). 2005 Sep; 53(9):1069-76.CP

Abstract

We discovered that the reactivity of some conjugated and electron-deficient hydrocarbons was quite different in the presence of transition metal catalysts. In this review we report our development and applications of the highly selective palladium and nickel-catalyzed cycloaddition reactions of unsaturated hydrocarbons such as conjugated enynes, electron-deficient allenes, and electron-deficient methylenecyclopropanes. Some homocoupling reactions as well as co-cyclization reactions were described. The efficient synthesis of 4--7 membered carbocycles was achieved.

Authors+Show Affiliations

Saito S
Department of Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Shinjuku, Tokyo, Japan. ssaito@rs.kagu.tus.ac.jp

MeSH

CatalysisCyclizationHydrocarbonsIndicators and ReagentsNickelPalladium

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't
Review

Language

eng

PubMed ID

16141570

Citation

Saito, Shinichi. "Development of New Cycloaddition Reactions Based On the Unique Reactivity of Unsaturated Hydrocarbons." Chemical & Pharmaceutical Bulletin, vol. 53, no. 9, 2005, pp. 1069-76.
Saito S. Development of new cycloaddition reactions based on the unique reactivity of unsaturated hydrocarbons. Chem Pharm Bull (Tokyo). 2005;53(9):1069-76.
Saito, S. (2005). Development of new cycloaddition reactions based on the unique reactivity of unsaturated hydrocarbons. Chemical & Pharmaceutical Bulletin, 53(9), 1069-76.
Saito S. Development of New Cycloaddition Reactions Based On the Unique Reactivity of Unsaturated Hydrocarbons. Chem Pharm Bull (Tokyo). 2005;53(9):1069-76. PubMed PMID: 16141570.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Development of new cycloaddition reactions based on the unique reactivity of unsaturated hydrocarbons. A1 - Saito,Shinichi, PY - 2005/9/6/pubmed PY - 2005/11/8/medline PY - 2005/9/6/entrez SP - 1069 EP - 76 JF - Chemical & pharmaceutical bulletin JO - Chem Pharm Bull (Tokyo) VL - 53 IS - 9 N2 - We discovered that the reactivity of some conjugated and electron-deficient hydrocarbons was quite different in the presence of transition metal catalysts. In this review we report our development and applications of the highly selective palladium and nickel-catalyzed cycloaddition reactions of unsaturated hydrocarbons such as conjugated enynes, electron-deficient allenes, and electron-deficient methylenecyclopropanes. Some homocoupling reactions as well as co-cyclization reactions were described. The efficient synthesis of 4--7 membered carbocycles was achieved. SN - 0009-2363 UR - https://www.unboundmedicine.com/medline/citation/16141570/Development_of_new_cycloaddition_reactions_based_on_the_unique_reactivity_of_unsaturated_hydrocarbons_ DB - PRIME DP - Unbound Medicine ER -