Tags

Type your tag names separated by a space and hit enter

Enantioselective reduction of imines catalyzed by a rhenium(V)-oxo complex.
J Am Chem Soc. 2005 Sep 14; 127(36):12462-3.JA

Abstract

An air- and moisture-tolerant enantioselective hydrosilylation of N-phosphinyl imines employing a chiral Re(V)-oxo complex as a catalyst is described. The chiral catalyst is a cyanobis(oxazoline) (CNbox)-ligated rhenium-oxo complex of the general formula (CNbox)Re(O)Cl2(OPPh3). Using this catalyst, a wide range of aromatic imines (including cyclic, acyclic, and heteroaromatic), alpha-iminoesters, and alpha,beta-unsaturated imines are reduced with good to excellent enantioselectivities.

Authors+Show Affiliations

Nolin KA
Department of Chemistry, University of California, Berkeley, California 94720, USA.
Ahn RW
No affiliation info available
Toste FD
No affiliation info available

MeSH

CatalysisCrystallography, X-RayIminesModels, MolecularMolecular ConformationOrganometallic CompoundsOxidation-ReductionRheniumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

16144373

Citation

Nolin, Kristine A., et al. "Enantioselective Reduction of Imines Catalyzed By a rhenium(V)-oxo Complex." Journal of the American Chemical Society, vol. 127, no. 36, 2005, pp. 12462-3.
Nolin KA, Ahn RW, Toste FD. Enantioselective reduction of imines catalyzed by a rhenium(V)-oxo complex. J Am Chem Soc. 2005;127(36):12462-3.
Nolin, K. A., Ahn, R. W., & Toste, F. D. (2005). Enantioselective reduction of imines catalyzed by a rhenium(V)-oxo complex. Journal of the American Chemical Society, 127(36), 12462-3.
Nolin KA, Ahn RW, Toste FD. Enantioselective Reduction of Imines Catalyzed By a rhenium(V)-oxo Complex. J Am Chem Soc. 2005 Sep 14;127(36):12462-3. PubMed PMID: 16144373.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Enantioselective reduction of imines catalyzed by a rhenium(V)-oxo complex. AU - Nolin,Kristine A, AU - Ahn,Richard W, AU - Toste,F Dean, PY - 2005/9/8/pubmed PY - 2006/2/4/medline PY - 2005/9/8/entrez SP - 12462 EP - 3 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 127 IS - 36 N2 - An air- and moisture-tolerant enantioselective hydrosilylation of N-phosphinyl imines employing a chiral Re(V)-oxo complex as a catalyst is described. The chiral catalyst is a cyanobis(oxazoline) (CNbox)-ligated rhenium-oxo complex of the general formula (CNbox)Re(O)Cl2(OPPh3). Using this catalyst, a wide range of aromatic imines (including cyclic, acyclic, and heteroaromatic), alpha-iminoesters, and alpha,beta-unsaturated imines are reduced with good to excellent enantioselectivities. SN - 0002-7863 UR - https://www.unboundmedicine.com/medline/citation/16144373/Enantioselective_reduction_of_imines_catalyzed_by_a_rhenium_V__oxo_complex_ DB - PRIME DP - Unbound Medicine ER -