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Cu(I)-catalyzed highly exo-selective and enantioselective [3 + 2] cycloaddition of azomethine ylides with acrylates.
Org Lett. 2005 Sep 15; 7(19):4241-4.OL

Abstract

[reaction: see text] A novel Cu(I)-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides with acrylates has been developed. Up to 98/2 exo/endo selectivity and up to 98% enantiomeric excess have been achieved.

Authors+Show Affiliations

Gao W
104 Chemistry Building, Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA.
Zhang X
No affiliation info available
Raghunath M
No affiliation info available

MeSH

AcrylatesAlkenesAzo CompoundsCatalysisCopperCyclizationGlycineLigandsMolecular StructureStereoisomerismSubstrate SpecificityThiosemicarbazones

Pub Type(s)

Journal Article
Research Support, N.I.H., Extramural
Research Support, U.S. Gov't, P.H.S.

Language

eng

PubMed ID

16146397

Citation

Gao, Wenzhong, et al. "Cu(I)-catalyzed Highly Exo-selective and Enantioselective [3 + 2] Cycloaddition of Azomethine Ylides With Acrylates." Organic Letters, vol. 7, no. 19, 2005, pp. 4241-4.
Gao W, Zhang X, Raghunath M. Cu(I)-catalyzed highly exo-selective and enantioselective [3 + 2] cycloaddition of azomethine ylides with acrylates. Org Lett. 2005;7(19):4241-4.
Gao, W., Zhang, X., & Raghunath, M. (2005). Cu(I)-catalyzed highly exo-selective and enantioselective [3 + 2] cycloaddition of azomethine ylides with acrylates. Organic Letters, 7(19), 4241-4.
Gao W, Zhang X, Raghunath M. Cu(I)-catalyzed Highly Exo-selective and Enantioselective [3 + 2] Cycloaddition of Azomethine Ylides With Acrylates. Org Lett. 2005 Sep 15;7(19):4241-4. PubMed PMID: 16146397.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Cu(I)-catalyzed highly exo-selective and enantioselective [3 + 2] cycloaddition of azomethine ylides with acrylates. AU - Gao,Wenzhong, AU - Zhang,Xumu, AU - Raghunath,Malati, PY - 2005/9/9/pubmed PY - 2006/8/5/medline PY - 2005/9/9/entrez SP - 4241 EP - 4 JF - Organic letters JO - Org Lett VL - 7 IS - 19 N2 - [reaction: see text] A novel Cu(I)-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides with acrylates has been developed. Up to 98/2 exo/endo selectivity and up to 98% enantiomeric excess have been achieved. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/16146397/Cu_I__catalyzed_highly_exo_selective_and_enantioselective_[3_+_2]_cycloaddition_of_azomethine_ylides_with_acrylates_ DB - PRIME DP - Unbound Medicine ER -