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AlMe3-promoted oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0). Observation of intermediate in methyl transfer process.
J Am Chem Soc. 2005 Sep 21; 127(37):12810-1.JA

Abstract

AlMe3 can promote the oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0) to give an intriguing nickel-aluminum dinuclear complex having a bridging methyl group, which might be an intermediate for the nickel-catalyzed cycloisomerization of o-allylacetophenone or o-allylbenzophenone.

Authors+Show Affiliations

Ogoshi S
Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan. ogoshi@chem.eng.osaka-u.ac.jp
Ueta M
No affiliation info available
Arai T
No affiliation info available
Kurosawa H
No affiliation info available

MeSH

AlkenesAluminumCrystallography, X-RayCyclizationKetonesModels, MolecularMolecular ConformationNickelOrganometallic CompoundsOxidation-Reduction

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

16159269

Citation

Ogoshi, Sensuke, et al. "AlMe3-promoted Oxidative Cyclization of Eta2-alkene and Eta2-ketone On Nickel(0). Observation of Intermediate in Methyl Transfer Process." Journal of the American Chemical Society, vol. 127, no. 37, 2005, pp. 12810-1.
Ogoshi S, Ueta M, Arai T, et al. AlMe3-promoted oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0). Observation of intermediate in methyl transfer process. J Am Chem Soc. 2005;127(37):12810-1.
Ogoshi, S., Ueta, M., Arai, T., & Kurosawa, H. (2005). AlMe3-promoted oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0). Observation of intermediate in methyl transfer process. Journal of the American Chemical Society, 127(37), 12810-1.
Ogoshi S, et al. AlMe3-promoted Oxidative Cyclization of Eta2-alkene and Eta2-ketone On Nickel(0). Observation of Intermediate in Methyl Transfer Process. J Am Chem Soc. 2005 Sep 21;127(37):12810-1. PubMed PMID: 16159269.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - AlMe3-promoted oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0). Observation of intermediate in methyl transfer process. AU - Ogoshi,Sensuke, AU - Ueta,Mizu, AU - Arai,Tomoya, AU - Kurosawa,Hideo, PY - 2005/9/15/pubmed PY - 2005/12/13/medline PY - 2005/9/15/entrez SP - 12810 EP - 1 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 127 IS - 37 N2 - AlMe3 can promote the oxidative cyclization of eta2-alkene and eta2-ketone on nickel(0) to give an intriguing nickel-aluminum dinuclear complex having a bridging methyl group, which might be an intermediate for the nickel-catalyzed cycloisomerization of o-allylacetophenone or o-allylbenzophenone. SN - 0002-7863 UR - https://www.unboundmedicine.com/medline/citation/16159269/AlMe3_promoted_oxidative_cyclization_of_eta2_alkene_and_eta2_ketone_on_nickel_0___Observation_of_intermediate_in_methyl_transfer_process_ DB - PRIME DP - Unbound Medicine ER -