Tags

Type your tag names separated by a space and hit enter

Cross and ring-closing metathesis of 1,3-diynes: metallotropic [1,3]-shift of ruthenium carbenes.
J Am Chem Soc. 2005 Sep 21; 127(37):12818-9.JA

Abstract

The regio- and stereoselective enyne CM and RCM reactions involving 1,3-diynes have been developed. The ring-closing metathesis of enediynes induces a facile metallotropic [1,3]-shift of alkynyl ruthenium carbene species, thereby providing a unique entry into the synthesis of fully conjugated 1,5-diene-3-ynes.

Authors+Show Affiliations

Kim M
Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706, USA.
Miller RL
No affiliation info available
Lee D
No affiliation info available

MeSH

AlkynesHydrocarbonsMethaneMolecular StructureOrganometallic CompoundsRuthenium

Pub Type(s)

Journal Article
Research Support, N.I.H., Extramural
Research Support, U.S. Gov't, Non-P.H.S.
Research Support, U.S. Gov't, P.H.S.

Language

eng

PubMed ID

16159273

Citation

Kim, Mansuk, et al. "Cross and Ring-closing Metathesis of 1,3-diynes: Metallotropic [1,3]-shift of Ruthenium Carbenes." Journal of the American Chemical Society, vol. 127, no. 37, 2005, pp. 12818-9.
Kim M, Miller RL, Lee D. Cross and ring-closing metathesis of 1,3-diynes: metallotropic [1,3]-shift of ruthenium carbenes. J Am Chem Soc. 2005;127(37):12818-9.
Kim, M., Miller, R. L., & Lee, D. (2005). Cross and ring-closing metathesis of 1,3-diynes: metallotropic [1,3]-shift of ruthenium carbenes. Journal of the American Chemical Society, 127(37), 12818-9.
Kim M, Miller RL, Lee D. Cross and Ring-closing Metathesis of 1,3-diynes: Metallotropic [1,3]-shift of Ruthenium Carbenes. J Am Chem Soc. 2005 Sep 21;127(37):12818-9. PubMed PMID: 16159273.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Cross and ring-closing metathesis of 1,3-diynes: metallotropic [1,3]-shift of ruthenium carbenes. AU - Kim,Mansuk, AU - Miller,Reagan L, AU - Lee,Daesung, PY - 2005/9/15/pubmed PY - 2005/12/13/medline PY - 2005/9/15/entrez SP - 12818 EP - 9 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 127 IS - 37 N2 - The regio- and stereoselective enyne CM and RCM reactions involving 1,3-diynes have been developed. The ring-closing metathesis of enediynes induces a facile metallotropic [1,3]-shift of alkynyl ruthenium carbene species, thereby providing a unique entry into the synthesis of fully conjugated 1,5-diene-3-ynes. SN - 0002-7863 UR - https://www.unboundmedicine.com/medline/citation/16159273/Cross_and_ring_closing_metathesis_of_13_diynes:_metallotropic_[13]_shift_of_ruthenium_carbenes_ DB - PRIME DP - Unbound Medicine ER -