Tags

Type your tag names separated by a space and hit enter

Pd-catalyzed asymmetric allylic amination using aspartic acid derived P-chirogenic diaminophosphine oxides: DIAPHOXs.
Org Lett. 2005 Sep 29; 7(20):4447-50.OL

Abstract

[reaction: see text] A Pd-catalyzed asymmetric allylic amination using aspartic acid derived P-chirogenic diaminophosphine oxides (DIAPHOXs) is described. Asymmetric allylic amination of both linear and cyclic substrates proceeded at room temperature to give the chiral allylic amines in 72-99% ee.

Authors+Show Affiliations

Nemoto T
Graduate School of Pharmaceutical Sciences, Chiba University, Yayoi-cho, Inage-ku, Chiba, 263-8522, Japan.
Masuda T
No affiliation info available
Akimoto Y
No affiliation info available
Fukuyama T
No affiliation info available
Hamada Y
No affiliation info available

MeSH

AminationAspartic AcidBenzylaminesCarbonatesCatalysisMolecular StructureOxidesOxygenasesPalladiumPhosphinesSolventsStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

16178555

Citation

Nemoto, Tetsuhiro, et al. "Pd-catalyzed Asymmetric Allylic Amination Using Aspartic Acid Derived P-chirogenic Diaminophosphine Oxides: DIAPHOXs." Organic Letters, vol. 7, no. 20, 2005, pp. 4447-50.
Nemoto T, Masuda T, Akimoto Y, et al. Pd-catalyzed asymmetric allylic amination using aspartic acid derived P-chirogenic diaminophosphine oxides: DIAPHOXs. Org Lett. 2005;7(20):4447-50.
Nemoto, T., Masuda, T., Akimoto, Y., Fukuyama, T., & Hamada, Y. (2005). Pd-catalyzed asymmetric allylic amination using aspartic acid derived P-chirogenic diaminophosphine oxides: DIAPHOXs. Organic Letters, 7(20), 4447-50.
Nemoto T, et al. Pd-catalyzed Asymmetric Allylic Amination Using Aspartic Acid Derived P-chirogenic Diaminophosphine Oxides: DIAPHOXs. Org Lett. 2005 Sep 29;7(20):4447-50. PubMed PMID: 16178555.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Pd-catalyzed asymmetric allylic amination using aspartic acid derived P-chirogenic diaminophosphine oxides: DIAPHOXs. AU - Nemoto,Tetsuhiro, AU - Masuda,Takamasa, AU - Akimoto,Yuichi, AU - Fukuyama,Takashi, AU - Hamada,Yasumasa, PY - 2005/9/24/pubmed PY - 2006/8/5/medline PY - 2005/9/24/entrez SP - 4447 EP - 50 JF - Organic letters JO - Org Lett VL - 7 IS - 20 N2 - [reaction: see text] A Pd-catalyzed asymmetric allylic amination using aspartic acid derived P-chirogenic diaminophosphine oxides (DIAPHOXs) is described. Asymmetric allylic amination of both linear and cyclic substrates proceeded at room temperature to give the chiral allylic amines in 72-99% ee. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/16178555/Pd_catalyzed_asymmetric_allylic_amination_using_aspartic_acid_derived_P_chirogenic_diaminophosphine_oxides:_DIAPHOXs_ DB - PRIME DP - Unbound Medicine ER -