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Organocatalytic asymmetric Michael addition of 2,4-pentandione to nitroolefins.
Org Lett. 2005 Oct 13; 7(21):4713-6.OL

Abstract

[reaction: see text] A novel binaphthyl-derived amine thiourea organocatalyst has been developed and demonstrated to efficiently catalyze Michael addition reactions (using as low as 1 mol % loading) of diketones to nitroalkenes with remarkably high enantioselectivities.

Authors+Show Affiliations

Wang J
Department of Chemistry, University of New Mexico, Albuquerque, New Mexico 87131-0001, USA.
Li H
No affiliation info available
Duan W
No affiliation info available
Zu L
No affiliation info available
Wang W
No affiliation info available

MeSH

AlkenesCatalysisModels, MolecularMolecular StructureNaphthalenesNitro CompoundsPentanonesStereoisomerismThiourea

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

16209517

Citation

Wang, Jian, et al. "Organocatalytic Asymmetric Michael Addition of 2,4-pentandione to Nitroolefins." Organic Letters, vol. 7, no. 21, 2005, pp. 4713-6.
Wang J, Li H, Duan W, et al. Organocatalytic asymmetric Michael addition of 2,4-pentandione to nitroolefins. Org Lett. 2005;7(21):4713-6.
Wang, J., Li, H., Duan, W., Zu, L., & Wang, W. (2005). Organocatalytic asymmetric Michael addition of 2,4-pentandione to nitroolefins. Organic Letters, 7(21), 4713-6.
Wang J, et al. Organocatalytic Asymmetric Michael Addition of 2,4-pentandione to Nitroolefins. Org Lett. 2005 Oct 13;7(21):4713-6. PubMed PMID: 16209517.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Organocatalytic asymmetric Michael addition of 2,4-pentandione to nitroolefins. AU - Wang,Jian, AU - Li,Hao, AU - Duan,Wenhu, AU - Zu,Liansuo, AU - Wang,Wei, PY - 2005/10/8/pubmed PY - 2006/8/9/medline PY - 2005/10/8/entrez SP - 4713 EP - 6 JF - Organic letters JO - Org Lett VL - 7 IS - 21 N2 - [reaction: see text] A novel binaphthyl-derived amine thiourea organocatalyst has been developed and demonstrated to efficiently catalyze Michael addition reactions (using as low as 1 mol % loading) of diketones to nitroalkenes with remarkably high enantioselectivities. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/16209517/Organocatalytic_asymmetric_Michael_addition_of_24_pentandione_to_nitroolefins_ DB - PRIME DP - Unbound Medicine ER -