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Palladium(II)-catalyzed intramolecular diamination of unfunctionalized alkenes.
J Am Chem Soc. 2005 Oct 26; 127(42):14586-7.JA

Abstract

Intramolecular diamination reactions are described which yield cyclic ureas as direct products of an oxidative alkene transformation in the presence of palladium acetate and iodosobenzene diacetate as terminal oxidant. The reaction is truly catalytic in metal catalyst and represents the proof of principle for this elusive type of alkene oxidation.

Authors+Show Affiliations

Streuff J
Kekulé-Institut für Organische Chemie und Biochemie, Gerhard-Domagk-Str. 1, D-53121 Bonn, Germany.
Hövelmann CH
No affiliation info available
Nieger M
No affiliation info available
Muñiz K
No affiliation info available

MeSH

AlkenesAminationCatalysisCrystallography, X-RayModels, MolecularMolecular StructurePalladiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

16231907

Citation

Streuff, Jan, et al. "Palladium(II)-catalyzed Intramolecular Diamination of Unfunctionalized Alkenes." Journal of the American Chemical Society, vol. 127, no. 42, 2005, pp. 14586-7.
Streuff J, Hövelmann CH, Nieger M, et al. Palladium(II)-catalyzed intramolecular diamination of unfunctionalized alkenes. J Am Chem Soc. 2005;127(42):14586-7.
Streuff, J., Hövelmann, C. H., Nieger, M., & Muñiz, K. (2005). Palladium(II)-catalyzed intramolecular diamination of unfunctionalized alkenes. Journal of the American Chemical Society, 127(42), 14586-7.
Streuff J, et al. Palladium(II)-catalyzed Intramolecular Diamination of Unfunctionalized Alkenes. J Am Chem Soc. 2005 Oct 26;127(42):14586-7. PubMed PMID: 16231907.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Palladium(II)-catalyzed intramolecular diamination of unfunctionalized alkenes. AU - Streuff,Jan, AU - Hövelmann,Claas H, AU - Nieger,Martin, AU - Muñiz,Kilian, PY - 2005/10/20/pubmed PY - 2006/1/25/medline PY - 2005/10/20/entrez SP - 14586 EP - 7 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 127 IS - 42 N2 - Intramolecular diamination reactions are described which yield cyclic ureas as direct products of an oxidative alkene transformation in the presence of palladium acetate and iodosobenzene diacetate as terminal oxidant. The reaction is truly catalytic in metal catalyst and represents the proof of principle for this elusive type of alkene oxidation. SN - 0002-7863 UR - https://www.unboundmedicine.com/medline/citation/16231907/Palladium_II__catalyzed_intramolecular_diamination_of_unfunctionalized_alkenes_ DB - PRIME DP - Unbound Medicine ER -