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Clay-fulleropyrrolidine nanocomposites.
J Am Chem Soc. 2006 May 10; 128(18):6154-63.JA

Abstract

In this work, we describe the insertion of a water-soluble bisadduct fulleropyrrolidine derivative into the interlayer space of three layered smectite clays. The composites were characterized by a combination of powder X-ray diffraction, transmission electron microscopy, X-ray photoemission and FTIR spectroscopies, and laser flash photolysis measurements. The experiments, complemented by computer simulations, give insight into the formation process, structural details, and properties of the fullerene/clay nanocomposites. The reported composite materials constitute a new hybrid system, where C(60) differs from its crystals or its solutions, and open new perspectives for the design and construction of novel C(60)-based organic/clay hybrid materials.

Authors+Show Affiliations

Gournis D
Department of Materials Science and Engineering, University of Ioannina, GR-45110 Ioannina, Greece. dgourni@cc.uoi.gr
Jankovic L
No affiliation info available
Maccallini E
No affiliation info available
Benne D
No affiliation info available
Rudolf P
No affiliation info available
Colomer JF
No affiliation info available
Sooambar C
No affiliation info available
Georgakilas V
No affiliation info available
Prato M
No affiliation info available
Fanti M
No affiliation info available
Zerbetto F
No affiliation info available
Sarova GH
No affiliation info available
Guldi DM
No affiliation info available

MeSH

Aluminum SilicatesClayComputer SimulationFullerenesMicroscopy, Electron, TransmissionNanocompositesPyrrolidinesSpectroscopy, Fourier Transform InfraredX-Ray Diffraction

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't
Research Support, U.S. Gov't, Non-P.H.S.

Language

eng

PubMed ID

16669685

Citation

Gournis, Dimitrios, et al. "Clay-fulleropyrrolidine Nanocomposites." Journal of the American Chemical Society, vol. 128, no. 18, 2006, pp. 6154-63.
Gournis D, Jankovic L, Maccallini E, et al. Clay-fulleropyrrolidine nanocomposites. J Am Chem Soc. 2006;128(18):6154-63.
Gournis, D., Jankovic, L., Maccallini, E., Benne, D., Rudolf, P., Colomer, J. F., Sooambar, C., Georgakilas, V., Prato, M., Fanti, M., Zerbetto, F., Sarova, G. H., & Guldi, D. M. (2006). Clay-fulleropyrrolidine nanocomposites. Journal of the American Chemical Society, 128(18), 6154-63.
Gournis D, et al. Clay-fulleropyrrolidine Nanocomposites. J Am Chem Soc. 2006 May 10;128(18):6154-63. PubMed PMID: 16669685.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Clay-fulleropyrrolidine nanocomposites. AU - Gournis,Dimitrios, AU - Jankovic,Lubos, AU - Maccallini,Enrico, AU - Benne,Darja, AU - Rudolf,Petra, AU - Colomer,Jean-François, AU - Sooambar,Chloé, AU - Georgakilas,Vasilios, AU - Prato,Maurizio, AU - Fanti,Marianna, AU - Zerbetto,Francesco, AU - Sarova,Ginka H, AU - Guldi,Dirk M, PY - 2006/5/4/pubmed PY - 2007/8/29/medline PY - 2006/5/4/entrez SP - 6154 EP - 63 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 128 IS - 18 N2 - In this work, we describe the insertion of a water-soluble bisadduct fulleropyrrolidine derivative into the interlayer space of three layered smectite clays. The composites were characterized by a combination of powder X-ray diffraction, transmission electron microscopy, X-ray photoemission and FTIR spectroscopies, and laser flash photolysis measurements. The experiments, complemented by computer simulations, give insight into the formation process, structural details, and properties of the fullerene/clay nanocomposites. The reported composite materials constitute a new hybrid system, where C(60) differs from its crystals or its solutions, and open new perspectives for the design and construction of novel C(60)-based organic/clay hybrid materials. SN - 0002-7863 UR - https://www.unboundmedicine.com/medline/citation/16669685/Clay_fulleropyrrolidine_nanocomposites_ DB - PRIME DP - Unbound Medicine ER -