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Achiral benzophenone ligand-rhodium complex with chiral diamine activator for high enantiocontrol in asymmetric transfer hydrogenation.
Chem Commun (Camb). 2006 Jun 14CC

Abstract

The chirality of an achiral benzophenone-based rhodium complex can be controlled by chiral diamines to afford significantly high enantioselectivity in the catalytic asymmetric transfer hydrogenation of ketones (up to 99% ee, 99% yield).

Authors+Show Affiliations

Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo, 152-8552, Japan. kmikami@o.cc.titech.ac.jpNo affiliation info availableNo affiliation info availableNo affiliation info available

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

16733581

Citation

Mikami, Koichi, et al. "Achiral Benzophenone Ligand-rhodium Complex With Chiral Diamine Activator for High Enantiocontrol in Asymmetric Transfer Hydrogenation." Chemical Communications (Cambridge, England), 2006, pp. 2365-7.
Mikami K, Wakabayashi K, Yusa Y, et al. Achiral benzophenone ligand-rhodium complex with chiral diamine activator for high enantiocontrol in asymmetric transfer hydrogenation. Chem Commun (Camb). 2006.
Mikami, K., Wakabayashi, K., Yusa, Y., & Aikawa, K. (2006). Achiral benzophenone ligand-rhodium complex with chiral diamine activator for high enantiocontrol in asymmetric transfer hydrogenation. Chemical Communications (Cambridge, England), (22), 2365-7.
Mikami K, et al. Achiral Benzophenone Ligand-rhodium Complex With Chiral Diamine Activator for High Enantiocontrol in Asymmetric Transfer Hydrogenation. Chem Commun (Camb). 2006 Jun 14;(22)2365-7. PubMed PMID: 16733581.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Achiral benzophenone ligand-rhodium complex with chiral diamine activator for high enantiocontrol in asymmetric transfer hydrogenation. AU - Mikami,Koichi, AU - Wakabayashi,Kazuki, AU - Yusa,Yukinori, AU - Aikawa,Kohsuke, Y1 - 2006/05/03/ PY - 2006/5/31/pubmed PY - 2007/4/25/medline PY - 2006/5/31/entrez SP - 2365 EP - 7 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) IS - 22 N2 - The chirality of an achiral benzophenone-based rhodium complex can be controlled by chiral diamines to afford significantly high enantioselectivity in the catalytic asymmetric transfer hydrogenation of ketones (up to 99% ee, 99% yield). SN - 1359-7345 UR - https://www.unboundmedicine.com/medline/citation/16733581/Achiral_benzophenone_ligand_rhodium_complex_with_chiral_diamine_activator_for_high_enantiocontrol_in_asymmetric_transfer_hydrogenation_ L2 - https://doi.org/10.1039/b517585b DB - PRIME DP - Unbound Medicine ER -