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Asymmetric Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric tridentate bis(oxazoline) and bis(thiazoline) zinc complexes.
J Am Chem Soc. 2006 Jun 14; 128(23):7418-9.JA

Abstract

The first asymmetric synthesis of 1,3-dinitro compounds through Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric chiral tridentate bis(oxazoline) and bis(thiazoline) zinc complexes was achieved with high enantioselectivities (up to 95% ee).

Authors+Show Affiliations

Lu SF
Beijing National Laboratory for Molecular Sciences, Peking University, Beijing 100871, China.
Du DM
No affiliation info available
Xu J
No affiliation info available
Zhang SW
No affiliation info available

MeSH

AlkanesAlkenesCarbonCatalysisModels, ChemicalNitro CompoundsOrganometallic CompoundsOxazolesThiazolesZinc

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

16756277

Citation

Lu, Shao-Feng, et al. "Asymmetric Michael Addition of Nitroalkanes to Nitroalkenes Catalyzed By C2-symmetric Tridentate Bis(oxazoline) and Bis(thiazoline) Zinc Complexes." Journal of the American Chemical Society, vol. 128, no. 23, 2006, pp. 7418-9.
Lu SF, Du DM, Xu J, et al. Asymmetric Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric tridentate bis(oxazoline) and bis(thiazoline) zinc complexes. J Am Chem Soc. 2006;128(23):7418-9.
Lu, S. F., Du, D. M., Xu, J., & Zhang, S. W. (2006). Asymmetric Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric tridentate bis(oxazoline) and bis(thiazoline) zinc complexes. Journal of the American Chemical Society, 128(23), 7418-9.
Lu SF, et al. Asymmetric Michael Addition of Nitroalkanes to Nitroalkenes Catalyzed By C2-symmetric Tridentate Bis(oxazoline) and Bis(thiazoline) Zinc Complexes. J Am Chem Soc. 2006 Jun 14;128(23):7418-9. PubMed PMID: 16756277.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Asymmetric Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric tridentate bis(oxazoline) and bis(thiazoline) zinc complexes. AU - Lu,Shao-Feng, AU - Du,Da-Ming, AU - Xu,Jiaxi, AU - Zhang,Shi-Wei, PY - 2006/6/8/pubmed PY - 2007/9/11/medline PY - 2006/6/8/entrez SP - 7418 EP - 9 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 128 IS - 23 N2 - The first asymmetric synthesis of 1,3-dinitro compounds through Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric chiral tridentate bis(oxazoline) and bis(thiazoline) zinc complexes was achieved with high enantioselectivities (up to 95% ee). SN - 0002-7863 UR - https://www.unboundmedicine.com/medline/citation/16756277/Asymmetric_Michael_addition_of_nitroalkanes_to_nitroalkenes_catalyzed_by_C2_symmetric_tridentate_bis_oxazoline__and_bis_thiazoline__zinc_complexes_ DB - PRIME DP - Unbound Medicine ER -