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Ruthenium-catalyzed alkylative lactonization and carbocyclization.
Org Lett. 2006 Aug 17; 8(17):3627-9.OL

Abstract

[reaction: see text] The cationic ruthenium complex [CpRu(NCCH3)3]PF6 promotes the coupling of monosubstituted allene carboxylic acids and simple alpha,beta-unsaturated olefins to form five- and six-membered lactones. The mild reaction conditions allow for the presence of various functional groups.

Authors+Show Affiliations

Department of Chemistry, Stanford University, Stanford, California 94305, USA. bmtrost@stanford.eduNo affiliation info available

Pub Type(s)

Journal Article
Research Support, N.I.H., Extramural
Research Support, U.S. Gov't, Non-P.H.S.

Language

eng

PubMed ID

16898777

Citation

Trost, Barry M., and Andrew McClory. "Ruthenium-catalyzed Alkylative Lactonization and Carbocyclization." Organic Letters, vol. 8, no. 17, 2006, pp. 3627-9.
Trost BM, McClory A. Ruthenium-catalyzed alkylative lactonization and carbocyclization. Org Lett. 2006;8(17):3627-9.
Trost, B. M., & McClory, A. (2006). Ruthenium-catalyzed alkylative lactonization and carbocyclization. Organic Letters, 8(17), 3627-9.
Trost BM, McClory A. Ruthenium-catalyzed Alkylative Lactonization and Carbocyclization. Org Lett. 2006 Aug 17;8(17):3627-9. PubMed PMID: 16898777.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Ruthenium-catalyzed alkylative lactonization and carbocyclization. AU - Trost,Barry M, AU - McClory,Andrew, PY - 2006/8/11/pubmed PY - 2007/6/15/medline PY - 2006/8/11/entrez SP - 3627 EP - 9 JF - Organic letters JO - Org Lett VL - 8 IS - 17 N2 - [reaction: see text] The cationic ruthenium complex [CpRu(NCCH3)3]PF6 promotes the coupling of monosubstituted allene carboxylic acids and simple alpha,beta-unsaturated olefins to form five- and six-membered lactones. The mild reaction conditions allow for the presence of various functional groups. SN - 1523-7060 UR - https://www.unboundmedicine.com/medline/citation/16898777/Ruthenium_catalyzed_alkylative_lactonization_and_carbocyclization_ L2 - https://doi.org/10.1021/ol0610136 DB - PRIME DP - Unbound Medicine ER -