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Search for solutions to the reactivity and selectivity problems in enyne metathesis.
Acc Chem Res. 2006 Aug; 39(8):509-19.AC

Abstract

Enyne metathesis is a powerful carbon-carbon bond-forming reaction to generate 1,3-dienes from an alkyne and an alkene. Different from the diene and diyne metathesis, the enyne metathesis suffers from both regio- and stereoselectivity problems, yet there is no general solution to these problems. This Account briefly describes the evolution of various new strategies and substrate platforms from these laboratories to address the reactivity and selectivity issues in the enyne metathesis processes.

Authors+Show Affiliations

Hansen EC
Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706, USA.
Lee D
No affiliation info available

MeSH

AlkenesAlkynesCarbonCatalysisModels, ChemicalMolecular StructureSiliconStereoisomerism

Pub Type(s)

Journal Article
Research Support, N.I.H., Extramural
Research Support, Non-U.S. Gov't
Research Support, U.S. Gov't, Non-P.H.S.

Language

eng

PubMed ID

16906747

Citation

Hansen, Eric C., and Daesung Lee. "Search for Solutions to the Reactivity and Selectivity Problems in Enyne Metathesis." Accounts of Chemical Research, vol. 39, no. 8, 2006, pp. 509-19.
Hansen EC, Lee D. Search for solutions to the reactivity and selectivity problems in enyne metathesis. Acc Chem Res. 2006;39(8):509-19.
Hansen, E. C., & Lee, D. (2006). Search for solutions to the reactivity and selectivity problems in enyne metathesis. Accounts of Chemical Research, 39(8), 509-19.
Hansen EC, Lee D. Search for Solutions to the Reactivity and Selectivity Problems in Enyne Metathesis. Acc Chem Res. 2006;39(8):509-19. PubMed PMID: 16906747.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Search for solutions to the reactivity and selectivity problems in enyne metathesis. AU - Hansen,Eric C, AU - Lee,Daesung, PY - 2006/8/16/pubmed PY - 2007/11/6/medline PY - 2006/8/16/entrez SP - 509 EP - 19 JF - Accounts of chemical research JO - Acc Chem Res VL - 39 IS - 8 N2 - Enyne metathesis is a powerful carbon-carbon bond-forming reaction to generate 1,3-dienes from an alkyne and an alkene. Different from the diene and diyne metathesis, the enyne metathesis suffers from both regio- and stereoselectivity problems, yet there is no general solution to these problems. This Account briefly describes the evolution of various new strategies and substrate platforms from these laboratories to address the reactivity and selectivity issues in the enyne metathesis processes. SN - 0001-4842 UR - https://www.unboundmedicine.com/medline/citation/16906747/Search_for_solutions_to_the_reactivity_and_selectivity_problems_in_enyne_metathesis_ L2 - https://doi.org/10.1021/ar050024g DB - PRIME DP - Unbound Medicine ER -