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High-precision catalysts: regioselective hydroformylation of internal alkenes by encapsulated rhodium complexes.
J Am Chem Soc. 2006 Sep 06; 128(35):11344-5.JA

Abstract

We report the formation of high-precision catalysts using encapsulated rhodium complexes. In the current example, the encapsulated rhodium catalyst shows unprecedented high selectivity in the rhodium-catalyzed hydroformylation of internal alkenes, forming predominantly one of the branched aldehydes. This catalyst system is the first example that is able to discriminate between carbon atoms C3 and C4 in trans-3-octene.

Authors+Show Affiliations

Kuil M
Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands.
Soltner T
No affiliation info available
van Leeuwen PW
No affiliation info available
Reek JN
No affiliation info available

MeSH

AldehydesAlkenesCatalysisIsomerismMolecular StructureRhodium

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

16939244

Citation

Kuil, Mark, et al. "High-precision Catalysts: Regioselective Hydroformylation of Internal Alkenes By Encapsulated Rhodium Complexes." Journal of the American Chemical Society, vol. 128, no. 35, 2006, pp. 11344-5.
Kuil M, Soltner T, van Leeuwen PW, et al. High-precision catalysts: regioselective hydroformylation of internal alkenes by encapsulated rhodium complexes. J Am Chem Soc. 2006;128(35):11344-5.
Kuil, M., Soltner, T., van Leeuwen, P. W., & Reek, J. N. (2006). High-precision catalysts: regioselective hydroformylation of internal alkenes by encapsulated rhodium complexes. Journal of the American Chemical Society, 128(35), 11344-5.
Kuil M, et al. High-precision Catalysts: Regioselective Hydroformylation of Internal Alkenes By Encapsulated Rhodium Complexes. J Am Chem Soc. 2006 Sep 6;128(35):11344-5. PubMed PMID: 16939244.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - High-precision catalysts: regioselective hydroformylation of internal alkenes by encapsulated rhodium complexes. AU - Kuil,Mark, AU - Soltner,Theresa, AU - van Leeuwen,Piet W N M, AU - Reek,Joost N H, PY - 2006/8/31/pubmed PY - 2007/8/9/medline PY - 2006/8/31/entrez SP - 11344 EP - 5 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 128 IS - 35 N2 - We report the formation of high-precision catalysts using encapsulated rhodium complexes. In the current example, the encapsulated rhodium catalyst shows unprecedented high selectivity in the rhodium-catalyzed hydroformylation of internal alkenes, forming predominantly one of the branched aldehydes. This catalyst system is the first example that is able to discriminate between carbon atoms C3 and C4 in trans-3-octene. SN - 0002-7863 UR - https://www.unboundmedicine.com/medline/citation/16939244/High_precision_catalysts:_regioselective_hydroformylation_of_internal_alkenes_by_encapsulated_rhodium_complexes_ L2 - https://doi.org/10.1021/ja063294i DB - PRIME DP - Unbound Medicine ER -