Asymmetric synergy between chiral dienes and diphosphines in cationic Rh(I)-catalyzed intramolecular [4 + 2] cycloaddition.
J Am Chem Soc. 2006 Oct 04; 128(39):12648-9.JA

Abstract

High enantioselective [4 + 2] cycloaddition can be achieved by cationic Rh complexes bearing not only chiral phosphine but also chiral diene. This is the first example of asymmetric synergy between chiral dienes and diphosphines.

Authors+Show Affiliations

Aikawa K

Department of Applied Chemistry, Tokyo Institute of Technology, Tokyo 152-8552, Japan.

Akutagawa S

No affiliation info available

Mikami K

No affiliation info available

Pub Type(s)

Journal Article

Language

eng

PubMed ID

17002349

Citation

Aikawa, Kohsuke, et al. "Asymmetric Synergy Between Chiral Dienes and Diphosphines in Cationic Rh(I)-catalyzed Intramolecular [4 + 2] Cycloaddition." Journal of the American Chemical Society, vol. 128, no. 39, 2006, pp. 12648-9.

Aikawa K, Akutagawa S, Mikami K. Asymmetric synergy between chiral dienes and diphosphines in cationic Rh(I)-catalyzed intramolecular [4 + 2] cycloaddition. J Am Chem Soc. 2006;128(39):12648-9.

Aikawa, K., Akutagawa, S., & Mikami, K. (2006). Asymmetric synergy between chiral dienes and diphosphines in cationic Rh(I)-catalyzed intramolecular [4 + 2] cycloaddition. Journal of the American Chemical Society, 128(39), 12648-9.

Aikawa K, Akutagawa S, Mikami K. Asymmetric Synergy Between Chiral Dienes and Diphosphines in Cationic Rh(I)-catalyzed Intramolecular [4 + 2] Cycloaddition. J Am Chem Soc. 2006 Oct 4;128(39):12648-9. PubMed PMID: 17002349.

* Article titles in AMA citation format should be in sentence-case

TY - JOUR T1 - Asymmetric synergy between chiral dienes and diphosphines in cationic Rh(I)-catalyzed intramolecular [4 + 2] cycloaddition. AU - Aikawa,Kohsuke, AU - Akutagawa,Susumu, AU - Mikami,Koichi, PY - 2006/9/28/pubmed PY - 2006/9/28/medline PY - 2006/9/28/entrez SP - 12648 EP - 9 JF - Journal of the American Chemical Society JO - J Am Chem Soc VL - 128 IS - 39 N2 - High enantioselective [4 + 2] cycloaddition can be achieved by cationic Rh complexes bearing not only chiral phosphine but also chiral diene. This is the first example of asymmetric synergy between chiral dienes and diphosphines. SN - 0002-7863 UR - https://www.unboundmedicine.com/medline/citation/17002349/Asymmetric_synergy_between_chiral_dienes_and_diphosphines_in_cationic_Rh_I__catalyzed_intramolecular_[4_+_2]_cycloaddition_ L2 - https://doi.org/10.1021/ja0650100 DB - PRIME DP - Unbound Medicine ER -

Tags

Asymmetric synergy between chiral dienes and diphosphines in cationic Rh(I)-catalyzed intramolecular [4 + 2] cycloaddition.J Am Chem Soc. 2006 Oct 04; 128(39):12648-9.JA