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Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes.
Chem Commun (Camb). 2006 Sep 14CC

Abstract

A rhodium/binap complex has been found to effectively catalyze the isomerization of unactivated internal alkynes to the corresponding 1,3-dienes in the presence of an azomethine imine as the reaction promoter.

Authors+Show Affiliations

Shintani R
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.
Duan WL
No affiliation info available
Park S
No affiliation info available
Hayashi T
No affiliation info available

MeSH

AlkenesAlkynesCatalysisMolecular StructureOrganometallic CompoundsRhodiumStereoisomerism

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

17047793

Citation

Shintani, Ryo, et al. "Rhodium-catalyzed Isomerization of Unactivated Alkynes to 1,3-dienes." Chemical Communications (Cambridge, England), 2006, pp. 3646-7.
Shintani R, Duan WL, Park S, et al. Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes. Chem Commun (Camb). 2006.
Shintani, R., Duan, W. L., Park, S., & Hayashi, T. (2006). Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes. Chemical Communications (Cambridge, England), (34), 3646-7.
Shintani R, et al. Rhodium-catalyzed Isomerization of Unactivated Alkynes to 1,3-dienes. Chem Commun (Camb). 2006 Sep 14;(34)3646-7. PubMed PMID: 17047793.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Rhodium-catalyzed isomerization of unactivated alkynes to 1,3-dienes. AU - Shintani,Ryo, AU - Duan,Wei-Liang, AU - Park,Soyoung, AU - Hayashi,Tamio, Y1 - 2006/08/02/ PY - 2006/10/19/pubmed PY - 2007/5/22/medline PY - 2006/10/19/entrez SP - 3646 EP - 7 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) IS - 34 N2 - A rhodium/binap complex has been found to effectively catalyze the isomerization of unactivated internal alkynes to the corresponding 1,3-dienes in the presence of an azomethine imine as the reaction promoter. SN - 1359-7345 UR - https://www.unboundmedicine.com/medline/citation/17047793/Rhodium_catalyzed_isomerization_of_unactivated_alkynes_to_13_dienes_ L2 - https://doi.org/10.1039/b605368h DB - PRIME DP - Unbound Medicine ER -