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Enantioselective phenylacetylene addition to aldehydes and ketones catalyzed by recyclable polymeric Zn(salen) complex.
Chirality. 2007 Jan; 19(1):82-8.C

Abstract

New polymeric Zn(salen) complex was employed in the enantioselective phenylacetylene addition to aldehydes and ketones to produce corresponding chiral secondary propargylic alcohols with yields (up to 96%) and enantioselectivity (up to 72%) and tertiary propargylic alcohols with yields (up to 79%) and enantioselectivity (up to 68%) at room temperature, with added advantage of four times reuse with retention of enantioselectivity.

Authors+Show Affiliations

Pathak K
Silicates and Catalysis Discipline, Central Salt and Marine Chemicals Research Institute (CSMCRI), Bhavnagar 364 002, Gujarat, India.
Bhatt AP
No affiliation info available
Abdi SH
No affiliation info available
Kureshy RI
No affiliation info available
Khan NU
No affiliation info available
Ahmad I
No affiliation info available
Jasra RV
No affiliation info available

MeSH

AcetyleneAldehydesCatalysisEthylenediaminesKetonesStereoisomerismTemperature

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

17094071

Citation

Pathak, Kavita, et al. "Enantioselective Phenylacetylene Addition to Aldehydes and Ketones Catalyzed By Recyclable Polymeric Zn(salen) Complex." Chirality, vol. 19, no. 1, 2007, pp. 82-8.
Pathak K, Bhatt AP, Abdi SH, et al. Enantioselective phenylacetylene addition to aldehydes and ketones catalyzed by recyclable polymeric Zn(salen) complex. Chirality. 2007;19(1):82-8.
Pathak, K., Bhatt, A. P., Abdi, S. H., Kureshy, R. I., Khan, N. U., Ahmad, I., & Jasra, R. V. (2007). Enantioselective phenylacetylene addition to aldehydes and ketones catalyzed by recyclable polymeric Zn(salen) complex. Chirality, 19(1), 82-8.
Pathak K, et al. Enantioselective Phenylacetylene Addition to Aldehydes and Ketones Catalyzed By Recyclable Polymeric Zn(salen) Complex. Chirality. 2007;19(1):82-8. PubMed PMID: 17094071.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Enantioselective phenylacetylene addition to aldehydes and ketones catalyzed by recyclable polymeric Zn(salen) complex. AU - Pathak,Kavita, AU - Bhatt,Achyut P, AU - Abdi,Sayed H R, AU - Kureshy,Rukhsana I, AU - Khan,Noor-Ul H, AU - Ahmad,Irshad, AU - Jasra,Raksh V, PY - 2006/11/10/pubmed PY - 2007/1/16/medline PY - 2006/11/10/entrez SP - 82 EP - 8 JF - Chirality JO - Chirality VL - 19 IS - 1 N2 - New polymeric Zn(salen) complex was employed in the enantioselective phenylacetylene addition to aldehydes and ketones to produce corresponding chiral secondary propargylic alcohols with yields (up to 96%) and enantioselectivity (up to 72%) and tertiary propargylic alcohols with yields (up to 79%) and enantioselectivity (up to 68%) at room temperature, with added advantage of four times reuse with retention of enantioselectivity. SN - 0899-0042 UR - https://www.unboundmedicine.com/medline/citation/17094071/Enantioselective_phenylacetylene_addition_to_aldehydes_and_ketones_catalyzed_by_recyclable_polymeric_Zn_salen__complex_ L2 - https://doi.org/10.1002/chir.20337 DB - PRIME DP - Unbound Medicine ER -