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Evolution of pyrrolidine-type asymmetric organocatalysts by "click" chemistry.
J Org Chem. 2006 Nov 24; 71(24):9244-7.JO

Abstract

Click chemistry has been employed to construct a library of the pyrrolidine-type asymmetric organocatalysts. The clicked organocatalysts were evaluated in asymmetric Michael addition of ketones to nitroolefins, showing good catalytic activity and stereoselectivity (up to 100% yield, syn:anti = 99:1, 96% ee).

Authors+Show Affiliations

Luo S
Beijing National Laboratory for Molecular Sciences, Center for Chemical Biology, Institute of Chemistry, Chinese Academy of Science, Beijing, 100080 China. luosz@iccas.ac.cn
Xu H
No affiliation info available
Mi X
No affiliation info available
Li J
No affiliation info available
Zheng X
No affiliation info available
Cheng JP
No affiliation info available

MeSH

CatalysisMagnetic Resonance SpectroscopyMass SpectrometryOrganic ChemicalsPyrrolidines

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

17109558

Citation

Luo, Sanzhong, et al. "Evolution of Pyrrolidine-type Asymmetric Organocatalysts By "click" Chemistry." The Journal of Organic Chemistry, vol. 71, no. 24, 2006, pp. 9244-7.
Luo S, Xu H, Mi X, et al. Evolution of pyrrolidine-type asymmetric organocatalysts by "click" chemistry. J Org Chem. 2006;71(24):9244-7.
Luo, S., Xu, H., Mi, X., Li, J., Zheng, X., & Cheng, J. P. (2006). Evolution of pyrrolidine-type asymmetric organocatalysts by "click" chemistry. The Journal of Organic Chemistry, 71(24), 9244-7.
Luo S, et al. Evolution of Pyrrolidine-type Asymmetric Organocatalysts By "click" Chemistry. J Org Chem. 2006 Nov 24;71(24):9244-7. PubMed PMID: 17109558.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - Evolution of pyrrolidine-type asymmetric organocatalysts by "click" chemistry. AU - Luo,Sanzhong, AU - Xu,Hui, AU - Mi,Xueling, AU - Li,Jiuyuan, AU - Zheng,Xiaoxi, AU - Cheng,Jin-Pei, PY - 2006/11/18/pubmed PY - 2007/2/21/medline PY - 2006/11/18/entrez SP - 9244 EP - 7 JF - The Journal of organic chemistry JO - J Org Chem VL - 71 IS - 24 N2 - Click chemistry has been employed to construct a library of the pyrrolidine-type asymmetric organocatalysts. The clicked organocatalysts were evaluated in asymmetric Michael addition of ketones to nitroolefins, showing good catalytic activity and stereoselectivity (up to 100% yield, syn:anti = 99:1, 96% ee). SN - 0022-3263 UR - https://www.unboundmedicine.com/medline/citation/17109558/Evolution_of_pyrrolidine_type_asymmetric_organocatalysts_by_"click"_chemistry_ L2 - https://doi.org/10.1021/jo061657r DB - PRIME DP - Unbound Medicine ER -