Asymmetric catalysis of Morita-Baylis-Hillman reactions by chiral phosphine Lewis bases bearing multiple phenol groups.Chirality. 2007 Feb; 19(2):124-8.C
Abstract
In the Morita-Baylis-Hillman (MBH) reactions of arylaldehydes with methyl vinyl ketone, it was observed that in the presence of a catalytic amount of a chiral phosphine Lewis base (CPLB) bearing multiple phenol groups, such as CPLB1 (10 mol %), the corresponding MBH adducts could be obtained in moderate to good yields with low to moderate ee's (4-45% ee) at ambient temperature (10 degrees C) in THF.
Pub Type(s)
Journal Article
Language
eng
PubMed ID
17117401
Citation
Shi, Min, et al. "Asymmetric Catalysis of Morita-Baylis-Hillman Reactions By Chiral Phosphine Lewis Bases Bearing Multiple Phenol Groups." Chirality, vol. 19, no. 2, 2007, pp. 124-8.
Shi M, Liu YH, Chen LH. Asymmetric catalysis of Morita-Baylis-Hillman reactions by chiral phosphine Lewis bases bearing multiple phenol groups. Chirality. 2007;19(2):124-8.
Shi, M., Liu, Y. H., & Chen, L. H. (2007). Asymmetric catalysis of Morita-Baylis-Hillman reactions by chiral phosphine Lewis bases bearing multiple phenol groups. Chirality, 19(2), 124-8.
Shi M, Liu YH, Chen LH. Asymmetric Catalysis of Morita-Baylis-Hillman Reactions By Chiral Phosphine Lewis Bases Bearing Multiple Phenol Groups. Chirality. 2007;19(2):124-8. PubMed PMID: 17117401.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR
T1 - Asymmetric catalysis of Morita-Baylis-Hillman reactions by chiral phosphine Lewis bases bearing multiple phenol groups.
AU - Shi,Min,
AU - Liu,Ying-Hao,
AU - Chen,Lian-Hui,
PY - 2006/11/23/pubmed
PY - 2006/11/23/medline
PY - 2006/11/23/entrez
SP - 124
EP - 8
JF - Chirality
JO - Chirality
VL - 19
IS - 2
N2 - In the Morita-Baylis-Hillman (MBH) reactions of arylaldehydes with methyl vinyl ketone, it was observed that in the presence of a catalytic amount of a chiral phosphine Lewis base (CPLB) bearing multiple phenol groups, such as CPLB1 (10 mol %), the corresponding MBH adducts could be obtained in moderate to good yields with low to moderate ee's (4-45% ee) at ambient temperature (10 degrees C) in THF.
SN - 0899-0042
UR - https://www.unboundmedicine.com/medline/citation/17117401/Asymmetric_catalysis_of_Morita_Baylis_Hillman_reactions_by_chiral_phosphine_Lewis_bases_bearing_multiple_phenol_groups_
L2 - https://doi.org/10.1002/chir.20313
DB - PRIME
DP - Unbound Medicine
ER -
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