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A simple asymmetric organocatalytic approach to optically active cyclohexenones.
Chem Commun (Camb). 2006 Dec 21CC

Abstract

Optically active 2,5-disubstituted-cyclohexen-2-one derivatives have been prepared in a one-pot process consisting of five reaction steps: an organocatalytic asymmetric conjugated addition of beta-ketoesters to alpha,beta-unsaturated aldehydes that proceeds in aqueous solutions or under solvent-free conditions has been implemented in a multi-step process.

Authors+Show Affiliations

Carlone A
Danish National Research Foundation: Center for Catalysis, Department of Chemistry, Aarhus University, DK 8000, Aarhus C, Denmark.
Marigo M
No affiliation info available
North C
No affiliation info available
Landa A
No affiliation info available
Jørgensen KA
No affiliation info available

MeSH

AldehydesCatalysisCyclohexanonesEstersKetonesMolecular StructureOptical RotationStereoisomerismWater

Pub Type(s)

Journal Article
Research Support, Non-U.S. Gov't

Language

eng

PubMed ID

17136250

Citation

Carlone, Armando, et al. "A Simple Asymmetric Organocatalytic Approach to Optically Active Cyclohexenones." Chemical Communications (Cambridge, England), 2006, pp. 4928-30.
Carlone A, Marigo M, North C, et al. A simple asymmetric organocatalytic approach to optically active cyclohexenones. Chem Commun (Camb). 2006.
Carlone, A., Marigo, M., North, C., Landa, A., & Jørgensen, K. A. (2006). A simple asymmetric organocatalytic approach to optically active cyclohexenones. Chemical Communications (Cambridge, England), (47), 4928-30.
Carlone A, et al. A Simple Asymmetric Organocatalytic Approach to Optically Active Cyclohexenones. Chem Commun (Camb). 2006 Dec 21;(47)4928-30. PubMed PMID: 17136250.
* Article titles in AMA citation format should be in sentence-case
TY - JOUR T1 - A simple asymmetric organocatalytic approach to optically active cyclohexenones. AU - Carlone,Armando, AU - Marigo,Mauro, AU - North,Chris, AU - Landa,Aitor, AU - Jørgensen,Karl Anker, Y1 - 2006/10/05/ PY - 2006/12/1/pubmed PY - 2007/2/21/medline PY - 2006/12/1/entrez SP - 4928 EP - 30 JF - Chemical communications (Cambridge, England) JO - Chem Commun (Camb) IS - 47 N2 - Optically active 2,5-disubstituted-cyclohexen-2-one derivatives have been prepared in a one-pot process consisting of five reaction steps: an organocatalytic asymmetric conjugated addition of beta-ketoesters to alpha,beta-unsaturated aldehydes that proceeds in aqueous solutions or under solvent-free conditions has been implemented in a multi-step process. SN - 1359-7345 UR - https://www.unboundmedicine.com/medline/citation/17136250/A_simple_asymmetric_organocatalytic_approach_to_optically_active_cyclohexenones_ L2 - https://doi.org/10.1039/b611366d DB - PRIME DP - Unbound Medicine ER -